3.2 mm HXY H13888

Probe description: PH MASDVT 850W6 BL3.2 X/Y/H

Additional components: Serial C: 22pF; Range Coil: 10 turns HZ09009

x/y combination	X f/MHz	Y f/MHz	Modification mode	Description insert	Part no:
²⁹Si/¹⁵N-²H	168.9	86-130.5	Serial-C in; λ/4	5 turns 12pF	HZ16569
¹³C/¹⁵N-²H	213.7	86 - 130.5	Serial-C in; λ/4	4 turns 8.2pF	HZ16499
¹³C/¹⁴N	213.7	61.4	range coil in; Serial C out; λ/4 at ¹⁴N position	4 turns 8.2pF	HZ16499
²³Na/¹⁵N-²H	224.8	86 -130.5	Serial-C in; λ/4	5 turns 6.8pF	HZ16570
²³Na/²⁹Si	224.8	168.9	Serial-C in; λ/2	5 turns 6.8pF	HZ16570
²³Na/¹⁴N	224.8	61.4	range coil in; Serial C out; λ/4 at ¹⁴N position	5 turns 6.8pF	HZ16570
²⁷Al/¹⁴N-²⁹Si	221.5	61.4-168.9	the same modifications as ²³Na	5 turns 6.8pF	HZ16571
¹¹B/¹⁷O-²⁹Si	272.7	115.2-168.9	Serial-C in; λ/2	6 turns 3.3pF	HZ16568

Probe Test Results (Stated 90^opulse lengths are the best achieved during installation. To reduce risk of damage to the probes, facility users should use slightly lower RF nutation frequencies (i.e. longer 90^o pulse lengths) were possible. Please discuss with the facility manager appropriate RF nutation frequencies for your experiments.)

Insert ²⁹Si/¹⁵N-²H

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ²⁹Si/¹⁵N-²H	Sample	Remarks
²⁹Si	3.25	-3	536	λ/4 + serial C	Si-Grease
¹⁵N	5.3	-2	556	λ/4 + serial C	Glycine (CP)
¹H	2.23	0	178	λ/4 + serial C	Glycine

Insert ¹³C/¹⁵N-²H :

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ¹³C/¹⁵N-²H	Sample	Remarks
⁷⁹Br	3.5	-1	368	λ/4 + serial C	KBr
¹³C	3.1	-0.6	350	λ/4 + serial C	Adamantane	line width 1.8Hz
¹H	2	-1.3	241	λ/4 + serial C	Adamantane	there is a ¹H background visible
¹³C	2.5	-.9	375	λ/4 + serial C	Glycine (CP)	S/N 79
¹H	1.95	-0.3	191	λ/4 + serial C	Glycine	100kHz for 50ms decoupling
¹⁵N	5.2/4.1	-0.77/-3	420/700	λ/4 + serial C	Glycine (CP/CP90) (enriched)
¹⁴N	5.5	-3	795	λ/4 at ¹⁴N +range coil	NH4Cl
¹⁴N	5	-4	1001	λ/4 at ¹⁴N +range coil	NH4Cl
¹H	1.8	-1.3	241	λ/4 at ¹⁴N +range coil	Adamantane
¹³C	3.4	-2.2	506	λ/4 at ¹⁴N +range coil	Adamantane

Insert ¹³C/¹⁵N-²H:

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ¹³C/¹⁵N-²H	Sample	Remarks
²⁹Si	6.5	-1	620	λ/2+ serial C	Si-Grease
¹³C	2.6	-0.9	375	λ/2 + serial C	Glycine (CP)	S/N 82
¹H	2.1	-0.3	191	λ/2 + serial C	Glycine

Insert ²³Na/¹⁵N-²H

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ²³Na/¹⁵N-²H	Sample	Remarks
²⁹Si	5.5	-2.5	477	λ/2 + serial C	Si-Grease
¹⁵N	4.8	-2	556	λ/4 + serial C	Glycine (CP)
¹H	2.2	0	179	λ/4 + serial C	Glycine
²³Na	2.88	-2	464	λ/4 + serial C	NaCl
²³Na	2.35	-2	464	λ/2 + serial C	NaCl

Insert ²⁷Al/¹⁵N-²H

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ²⁷Al/¹⁵N-²H	Sample	Remarks
¹⁵N	4.8	-2	556	λ/4 + serial C	Glycine (CP)
¹H	2.15	0	178	λ/4 + serial C	Glycine

Insert ¹¹B/¹⁷O-²⁹Si)

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ¹¹B/¹⁷O-²⁹Si	Sample	Remarks
¹¹B	1.55	-2	395	λ/2 + serial C	Borax
²⁹Si	5.1	-3	536	λ/2 + serial C	Si-Grease

DR mode

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration	Sample	Remarks
¹³C	2.17	-0.6	350	λ/2	Adamantane
¹H	1.65	-1.3	241	λ/2	Adamantane
¹³C	1.7	1	242	λ/2	Glycine (CP)	S/N 121
¹H	1.95	-0.3	191	λ/4	Glycine
¹⁵N	3.8	-0.77	420	λ/4 1hole down	Glycine (CP)	S/N 15
¹H	2.25	1	142	λ/4 1hole down	Glycine
¹⁴N	3.7	-3	715	λ/4 1hole down	NH4Cl

Tuning range (measured on the bench, double resonnace mode 1H-X )

λ/2 mode	165→283MHz	Includes ²⁹Si(168.871), ¹²⁷I(170.064), ²⁰⁷Pb( 177.825), ¹¹¹Cd(180.332), ¹⁶⁵Ho(181.390), ¹⁹⁵Pt(182.723), ¹¹³In(185.859), ¹¹⁵In(186.257), ¹¹³Cd(188.642), ⁹⁹Tc(191.321), ¹⁸⁵Re(191.459), ¹⁸⁷Re(193.389), ⁵⁹Co(201.680), ¹²¹Sb(203.410), ⁶⁹Ga(204.012), ¹⁵⁹Tb(204.340), ⁴⁵Sc(206.480), ⁹³Nb(208.047), ⁵⁵Mn(210.708), ¹⁵¹Eu(211.310), ⁷⁹Br(212.959), ¹³C(213.733), ²⁷Al (221.483), ¹²³Te(222.443), ⁵¹V(223.575), ²³Na(224.841), ⁶³Cu(225.382), ⁸¹Br(229.555), ¹²⁹Xe(236.387), ⁶⁵Cu(241.431), ⁷¹Ga(259.222), ¹⁴¹Pr(260.270), ¹²⁵Te(268.173), ¹¹B(272.714), ¹¹⁵Sn(278.109), ⁸⁷Rb(278.124),
λ/4 mode	100→228 MHz	Inlcudes: ¹⁸¹Ta( 101.912), ¹²³Sb( 110.153), ¹³³Cs(111.487), ¹³⁸La( 112.152), ¹⁷O(115.230), ⁹Be( 119.440), ¹³⁹La(120.068), ⁶ Li(125.087), ²H(130.480), ²⁰⁹Bi(136.589), ⁷⁵As(145.542), ¹⁷¹Yb(148.744), ¹⁹⁹Hg(152.242), ⁷⁷Se(162.108), ²⁹Si(168.871), ¹²⁷I(170.064), ²⁰⁷Pb( 177.825), ¹¹¹Cd( 180.332), ¹⁶⁵Ho(181.390), ¹⁹⁵Pt(182.723), ¹¹³In(185.859), ¹¹⁵In(186.257), ¹¹³Cd(188.642), ⁹⁹Tc(191.321), ¹⁸⁵Re(191.459), ¹⁸⁷Re(193.389), ⁵⁹Co(201.680), ¹²¹Sb(203.410), ⁶⁹Ga(204.012), ¹⁵⁹Tb(204.340), ⁴⁵Sc(206.480), ⁹³Nb(208.047), ⁵⁵Mn(210.708), ¹⁵¹Eu(211.310), ⁷⁹Br(212.959), ¹³C(213.733), ²⁷Al (221.483), ¹²³Te(222.443), ⁵¹V(223.575), ²³Na(224.841), ⁶³Cu(225.382)

Temperature calibration for the 3.2 mm HXY probe spinning at 20 kHz.

Bruker indicated
temperature (^oC)

Real temperature
calibrated with lead nitrate (^oC)

111

133*

152*

116

178*

*Booster connected