Jack Emerson-King

Jack Emerson-King

PhD: 2015 – 2019

Rhodium and iridium phosphine complexes: Approaches for studying the coordination chemistry of weakly interacting substrates

Linkedin: profileLink opens in a new window ORCID: 0000-0002-0309-8344Link opens in a new window

Publications

8. J. E. Smart, J. Emerson-King, R. J. Jeans, T. M. Hood, S. Lau, A. Bara-Estaún, U. Hintermair, P. G. Pringle, and A. B. Chaplin. A Resorcin[4]arene-Based Phosphite-Phosphine Ligand for the Branched-Selective Hydroformylation of Alkyl Alkenes. ACS Catal. 2024, 14, 11803–11807.
7. J. Emerson-King and A. B. Chaplin. Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand. Dalton Trans. 2023, 52, 5044–5046Link opens in a new window.
6. J. Emerson-King, S. Pan, M. R. Gyton, R. Tonner-Zech and A. B. Chaplin. Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand. Chem. Commun. 2023, 59, 2150–2152Link opens in a new window.
5. J. Emerson-King, I. Prokes and A. B. Chaplin. Rhodium(III) Complexes Featuring Coordinated CF₃ Appendages. Chem. Eur. J. 2019, 25, 6317–6319.
4. R. C. Knighton, J. Emerson-King, J. P. Rourke, C. A. Ohlin and A. B. Chaplin. Solution, Solid-State, and Computational Analysis of Agostic Interactions in a Coherent Set of Low-Coordinate Rhodium(III) and Iridium(III) Complexes. Chem. Eur. J. 2018, 24, 4927–4938Link opens in a new window (Hot Paper).
3. J. Emerson-King, R. C. Knighton, M. R. Gyton and A. B. Chaplin. Rotaxane synthesis exploiting the M(I)/M(III) redox couple. Dalton Trans. 2017, 46, 11645–11655Link opens in a new window.
2. S. A. Hauser, J. Emerson-King, S. Habershon, and A. B. Chaplin. UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(I) pincer complex. Chem. Commun., 2017, 53, 3634–3636Link opens in a new window.
1. J. Emerson-King, S. A. Hauser and A. B. Chaplin. C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Org. Biomol. Chem., 2017, 15, 787–789Link opens in a new window.