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Chemistry Chaplin Group

Matthew Gyton

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Research

PDRA investigating the synthesis and applications of rhodium complexes of phosphine-based macrocyclic and interlocked ligands.

ORCID = 0000-0002-7565-5154

Background

2019: Dalton Transactions Outstanding Oral Presentation Prize – RSC Dalton Division Southern Regional Meeting
2019: RSC Dalton Division Travel Grant
2015 – present: ERC funded PDRA, University of Warwick.
2010 – 2015: PhD (Cole group), University of New South Wales.

2006 – 2009: BSc(Hons), University of New South Wales.

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Contact

Email: m.gyton(at)warwick.ac.uk
Twitter: @MatthewGyton

Publications and contributions to symposia

  1. M. R. Gyton, A. E. Kynman, B. Leforestier, A. Gallo, J. R. Lewandowski and A. B. Chaplin*. Isolation and structural characterisation of rhodium(III) η2–fluoroarene complexes: experimental verification of predicted regioselectivity. Dalton Trans. 2020, in the press.
  2. B. Leforestier, M. R. Gyton and A. B. Chaplin. Synthesis and group 9 complexes of macrocyclic PCP and POCOP pincer ligands. Dalton Trans. 2020, in the press.
  3. C. M. Storey, A. Kalpokas, M. R. Gyton, T. Krämer and A. B. Chaplin. A Shape Changing Tandem Rh(CNC) Catalyst: Preparation of Bicyclo[4.2.0]octa-1,5,7-trienes From Terminal Aryl Alkynes. Chem. Sci. 2020, in the press.
  4. T. M. Hood, M. R. Gyton and A. B. Chaplin. Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands. Dalton Trans. 2020, in the press.

  5. M. R. Gyton, T. M. Hood, B. Leforestier and A. B. Chaplin. A convenient method for the generation of [Rh(PNP)]+and [Rh(PONOP)]+ fragments: reversible vinylidene formation and nitrous oxide complexes. 5th RSC Dalton Division Southern Regional Meeting, Oxford, UK, 2019.

  6. M. R. Gyton, B. Leforestier and A. B. Chaplin. Rhodium(I) Pincer Complexes of Nitrous Oxide. Angew. Chem. Int. Ed. 2019, 58, 15295 – 15298.

  7. M. R. Gyton, T. M. Hood and A. B. Chaplin. A convenient method for the generation of [Rh(PNP)]+ and [Rh(PONOP)]+ fragments: reversible formation of vinylidene derivatives. 12th Australasian Organometallics Meeting (OZOM12), Melbourne, Australia, 2019.

  8. M. R. Gyton, T. M. Hood and A. B. Chaplin. A convenient method for the generation of [Rh(PNP)]+ and [Rh(PONOP)]+ fragments: reversible formation of vinylidene derivatives. XXIII EuCheMS International Conference on Organometallic Chemistry (EuCOMC XXIII), Helsinki, Finland, 2019.

  9. M. R. Gyton,* M. Bhadbhade and M. L. Cole. Z. Anorg. Allg. Chem. 2019, 645, 768 – 776.
  10. T. M. Hood, B. Leforestier, M. R. Gyton and A. B. Chaplin. Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes. Inorg. Chem. 2019, 58, 7593 – 7601.
  11. M. R. Gyton, B. Leforestier and A. B. Chaplin. Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen. RSC Sir Geoffrey Wilkinson Dalton poster symposium, London, UK, 2019.
  12. M. R. Gyton, T. M. Hood and A. B. Chaplin. A Convenient Method for the Generation of {Rh(PNP)}+ and {Rh(PONOP)}+ Fragments: Reversible Formation of Vinylidene Derivatives. Dalton Trans. 2019, 48, 2877 – 2880.
  13. M. R. Gyton, B. Leforestier and A. B. Chaplin. Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen. Organometallics 2018, 37, 3963 – 3971.
  14. M. R. Gyton, B. Leforestier and A. B. Chaplin. Rhodium(III) and iridium(III) complexes of a NHC-based macrocycle: synthesis and reactivity. XXVIII International Conference on Organometallic Chemistry (ICOMC), Florence, Italy, 2018.
  15. C. M. Storey, M. R. Gyton, R. E. Andrew and A. B. Chaplin. Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching. Angew. Chem. Int. Ed. 2018, 57, 12003 – 12006.
  16. M. R. Gyton, B. Leforestier and A. B. Chaplin. Rhodium(III) and iridium(III) complexes of a NHC-based macrocycle: synthesis and reactivity. Dalton 2018 – A Joint Meeting of Dalton Division Interest Groups, Coventry, UK, 2018.
  17. M. R. Gyton, B. Leforestier and Adrian B. Chaplin. Rhodium(III) and iridium(III) complexes of a NHC-based macrocycle: synthesis and reactivity. Dalton Younger Members Event (DYME), Bath, UK, 2017.
  18. J. Emerson-King, R. C. Knighton, M. R. Gyton and A. B. Chaplin. Rotaxane synthesis exploiting the M(I)/M(III) redox couple. Dalton Trans. 2017, 46, 11645 – 11655.
  19. M. R. Gyton and A. B. Chaplin. Late Transition Metal Catalysed C(sp3)–C(sp3) coupling reactions, Dalton 2016 – A Joint Meeting of Dalton Division Interest Groups, Coventry, UK, 2016.
  20. S. K. Furfari, M. R. Gyton and M. L. Cole, Chem. Commun. 2015, 51, 74 – 76.
  21. M. R. Gyton, M. L. Cole and J. B. Harper, Chem. Commun. 2011, 47, 9200 – 9202.
  22. M. L. Cole, M. R. Gyton and J. B. Harper, Aust. J. Chem. 2011, 64, 1133 – 1140.