PhD: 2017 - 2022

One-electron chemistry of palladium, platinum, and gold bis(phosphine) complexes

Destination: Scientist Team Leader at C-Tech innovation.

ORCID: 0000-0002-6913-343XLink opens in a new window

Publications

6. M. J. G. Sinclair, N. Roig, N. Tsoureas, M. Alonso, and A. B. Chaplin. Synthesis and characterisation of {PdNO}¹⁰ pincer complexes. Eur. J. Inorg. Chem. 2025, in press.
5. M. J. G. Sinclair, N. Roig, M. R. Gyton, N. Tsoureas, F. G. N. Cloke, M. Alonso, and A. B. Chaplin. T-Shaped Palladium and Platinum {MNO}¹⁰ Nitrosyl Complexes. Inorg. Chem. 2024, 63, 1709 – 1713Link opens in a new window.
4. T. Krämer, M. R. Gyton, I. Bustos, M. J. G. Sinclair, S.-y. Tan, C. J. Wedge, S. A. Macgregor and A. B. Chaplin. Stability and C–H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism. J. Am. Chem. Soc. 2023, 145, 14087 – 14100Link opens in a new window.
3. M. J. G. Sinclair and A. B. Chaplin. Heterolytic carbon–iodine bond cleavage by a palladium(I) metalloradical. Dalton Trans. 2022, 51, 11617 – 11619Link opens in a new window.
2. M. J. G. Sinclair and A. B. Chaplin. Oxidative ring expansion of a low-coordinate palladacycle: synthesis of a robust T-shaped alkylpalladium(II) complex. Inorg. Chim. Acta 2020, 513, 119948Link opens in a new window.
1. Q. Simpson, M. J. G. Sinclair, D. W. Lupton, A. B. Chaplin and J. F. Hooper. Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I). Org. Lett. 2018, 20, 5537 – 5540Link opens in a new window.