Skip to main content Skip to navigation


Book chapters

11 Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization from Surfaces, Zhao, Y.; Perrier, S. in Adv. Polym. Sci. “Controlled Radical Polymerization at and from Solid Surfaces”, Vana, P. ed., 2015, 77-106

10 Kinetic Studies of Elementary Reactions in SET-LRP / SARA ATRP, Nicolas, J.; Perrier, S.; Harrisson, S. in ACS Symp. Ser., K. Matyaszewski, ed., in Press

9 Synthesis Strategies for the Design of Peptide / Polymer Conjugates, Dehn, S.; Chapman, R.; Jolliffe, K.A.; Perrier, S. in Encyclopedia of Biomedical Polymers and Polymeric Biomaterials, M.K. Mishra ed., CRC Press, February 2014.

8 Dendritic Polymers from Thiol–Yne Reaction, Barbey, R.; Perrier, S. in Thiol-X Chemistries in Polymer and Materials Science, A. B. Lowe and C. N. Bowman eds., RSC Publishing, in press.

7 Macromolecular Engineering via RAFT Chemistry: From Sequential to Modular Design, Barner-Kowollik, C.; Blinco, J.P.; Perrier, S. in Synthesis of Polymers, D.A. Schlüter, C.J.Hawker and J. Sakamoto eds., 2012, Wiley-VCH, Verlag GmbH & Co. KGaA, Weinheim, 601-626.

6 RAFT Polymerization: A Powerful Tool for the Synthesis and Study of Oligomers, Siauw, M.; Hawkett, B.S.; Perrier, S. in ACS Symp. Ser., K. Matyaszewski, B.S. Sumerlin, N.V. Tsarevsky, eds., 2012, 1101, (Progress in Controlled Radical Polymerization: Materials and Applications), 13-25.

5 Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization: Mechanism, Process and Applications, Barner-Kowollik, C.; Blinco, J. P.; Destarac, M.; Thurecht, K.J.; Perrier, S. in Encyclopedia of Radicals in Chemistry, Biology & Materials, A. Studer, C. Chatgilialoglu eds., 2012, Wiley-VCH, Verlag GmbH & Co. KGaA, Weinheim, 1895-1930.

4 RAFT Polymerization, a Versatile Tool for the Production of Functional Soft Nanoparticles, Jitchum, V.; Kakwere, H.; Ladmiral, V.; Perrier, S. ACS Symp. Ser., K. Matyaszewski, ed., 2009, 1024, (Controlled/living radical polymerization: Progress in RAFT, NMP & OMRP), 279-292.

3 Polymers with well-defined end groups via RAFT – synthesis, applications and post modifications, Barner, L., Perrier, S. Handbook of RAFT polymerization, C. Barner-Kowollik, ed., Wiley-VCH, Weinheim 2008, 455-482.

2 Progress in RAFT/MADIX polymerization: synthesis, use, and recovery of chain transfer agents, Perrier, S., Takolpuckdee, P., Brown, L. S., Legge, T. M., Roy, D., Wood, M. R., Rannard, S. P., Duncalf, D. J. ACS Symp. Ser. , K. Matyaszewski, ed., 2006, 944 (Controlled/living radical polymerization), 438-454.

1 In situ NMR monitoring of living radical polymerization: reaction kinetics and catalyst evolution, Perrier, S. and D.M. Haddleton, In situ spectroscopy of monomer and polymer synthesis, J.E. Puskas, T.E. Long, and R.F. Storey, eds, Kluwer Academic/Plenum Publishers, New York 2003, 125-146.

Journal articles

218. Gurnani, P; Perrier, S, Controlled radical polymerisation in dispersed systems for biological applications, Progress in Polymer Science, 2019, In press DOI: 10.1016/j.progpolymsci.2020.101209

217. Tchoupa, A.K; Jones, R.A; Kuroki, A; Alam, M.T.; Perrier, S; Chen, Y; Unnikrishnan, M, The type VII secretion system protects Staphylococcus aureus against antimicrobial host fatty acids, BioRxiv, 2019, pre-print, DOI: 10.1101/572172

216. Hartlieb, M.; Catrouillet, S.; Kuroki, A.; Sanchez-Cano, C.; Peltier, R.; Perrier, S, Stimuli-responsive membrane activity of cyclic-peptide–polymer conjugates, Chem. Sci., 2019, 10, 5476-5483, DOI: 10.1039/C9SC00756C

215. Zhao, R; Zhou, Y; Jie, K; Yang, J; Perrier, S; Huang, F, Fluorescent Supramolecular Polymersomes Based on Pillararene Paraquat Molecular Recognition for pH-controlled Drug Release, Chin J Polym Sci, 2019, In press, DOI: 10.1007/s10118-019-2305

214. Rho, J.Y.; Cox, H.; Mansfield, E.D.H.; Ellacott, S.H.; Peltier, R; Brendel, J.C.; Hartlieb, M; Waigh, T.A.; Perrier, S, Dual self-assembly of supramolecular peptide nanotubes to provide stabilisation in water. Nat Commun, 2019,10, 4708, DOI:10.1038/s41467-019-12586-8

213. Song, Q; Yang, J; Hall, S.C.L; Gurnani, P; Perrier, S, Pyridyl Disulfide Reaction Chemistry: An Efficient Strategy towards Redox-Responsive Cyclic Peptide-Polymer Conjugates, ACS Macro Lett. 2019 8, 10, 1347-1352, DOI:10.1021/acsmacrolett.9b00538

212. Clothier, G.K.K.; Guimarães, T.R.; Khan, M; Moad, G; Perrier, S; Zetterlund, P.B, Exploitation of the Nanoreactor Concept for Efficient Synthesis of Multiblock Copolymers via MacroRAFT-Mediated Emulsion Polymerization, ACS Macro Lett. 2019 , 8, 8, 989-995, DOI: 10.1021/acsmacrolett.9b00534

211.Guimarães, T.R.; Khan, M; Kuchel, R.P.; Morrow I.C.; Minami, H; Moad, G; Perrier, S; Zetterlund, P.B, Nano-Engineered Multiblock Copolymer Nanoparticles via Reversible Addition–Fragmentation Chain Transfer Emulsion Polymerization, Macromolecules , 2019 , 52, 8, 2965-2974, DOI: 10.1021/acs.macromol.9b00257

210. Kuroki, A; Kengmo Tchoupa, A; Hartlieb, M; Peltier, R; Locock, K.E.S.; Unnikrishnan, M; Perrier, S, Targeting intracellular, multi-drug resistant Staphylococcus aureus with guanidinium polymers by elucidating the structure-activity relationship, Biomaterials , 2019 , 217, 119249, DOI: 10.1016/j.biomaterials.2019.119249

209. Moriceau. G; Lester. D; Pappas. G.S.; O'Hora, P; Winn, J; Smith,T; Perrier,S, Well-Defined Alkyl Functional Poly(Styrene-co-Maleic Anhydride) Architectures as Pour Point and Viscosity Modifiers for Lubricating Oil, Energy Fuels , 2019, 33, 8, 7257-7264, DOI: 10.1021/acs.energyfuels.9b01470

208. Li, J; Zhang, M; Pan, X; Zhang, Z; Perrier, S; Zhu, J; Zhu, X, Visible light induced controlled cationic polymerization by in situ generated catalyst from manganese carbonyl, Chem. Commun., 2019, 55, 7045-7048, DOI: 10.1039/C9CC03317C

207. Brendel, J.C.; Catrouillet, S; Sanchis, J; Jolliffe, K.A.; Perrier, S, Shaping block copolymer micelles by supramolecular polymerization : making ‘tubisomes’. Polymer Chemistry, 2019, 10 (20). pp. 2616-2625. doi:10.1039/C9PY00179D

206. Song, Q; Yang, J; Rho, J.Y.; Perrier, Sébastien, Supramolecular switching of the self-assembly of cyclic peptide–polymer conjugates via host–guest chemistry, Chemical Communications, 2019, 55 (36). pp. 5291-5294, DOI:10.1039/c9cc01914f

205. Cook, A.B.; Perrier, S., Branched and Dendritic Polymer Architectures: Functional Nanomaterials for Therapeutic Delivery, Advanced Functional Materials , 2019 , Advance article, DOI: 10.1002/adfm.201901001

204. Gurnani, P.; Cook, A.B.; Richardson, R.A.E.; Perrier, S., A study on the preparation of alkyne functional nanoparticles via RAFT emulsion polymerisation, Polymer Chemistry, 2019, 10, 1452-1459, DOI: 10.1039/C8PY01579A

203. Moriceau, G.; Tanaka, J.; Lester, D.; Pappas, G.S.; Cook, A.B.; P. Winn, J.; Smith, T.; Perrier, S., Influence of Grafting Density and Distribution on Material Properties Using Well-Defined Alkyl Functional Poly(Styrene-co-Maleic Anhydride) Architectures Synthesized by RAFT, Macromolecules 2019, 52 (4), pp 1469–1478, DOI: 10.1021

202. Tanaka, J.; Song, J-I.; Lunn, A.M.; Hand, R.A.; Häkkinen, S.; Schiller, T.L.; Perrier, S.; Davis, T.P.; Wilson, P.; Polymeric arsenicals as scaffolds for functional and responsive hydrogels, Journal of Materials Chemisty B, 2019, Advance article, DOI: 10.1039/C8TB02569J

201. Martin, L.; Gurnani, P.; Zhang, J.; Hartlieb, M.; Cameron, N.R.; Eissa, A.M.; Perrier, S., Polydimethylsiloxane-Based Giant Glycosylated Polymersomes with Tunable Bacterial Affinity, Biomacromolecules, 2019, Article ASAP, DOI: 10.1021/acsbiomac.8b01709

200. Tanaka, J.; Moriceau, G.; Cook, A.; Kerr, A.; Zhang, J.; Peltier, R.; Perrier, S.; Davis, T.P.; WIlson, P., Tuning the Structure, Stability, and Responsivity of Polymeric Arsenical Nanoparticles Using Polythiol Cross-Linkers, Macromolecules, 2019, 52 (3), pp 992-1003, DOI: 10.1021/acs.macromol.8b02459

199. Tanaka, J.; Gurnani, P.; Cook, A.B.; Häkkinen, S.; Zhang, J.; Yang, J.; Kerr, A.; Haddleton, D.M.; Perrier, S.; Wilson, P., Microscale synthesis of multiblock copolymers using ultrafast RAFT polymerisation, Polymer Chemistry 2019 Advance article DOI: 10.1039/C8PY01437J

198. Khan, M.; Guimarães, T.R.; Zhou, D.; Moad, G.; Perrier, S.; Zetterlund, P.B., Exploitation of Compartmentalization in RAFT miniemulsion Polymerization to Increase the Degree of Livingness, Journal of Polymer Science Part A: Polymer Chemistry 2019 Advance article DOI: 10.1002/pola.29329

197. Cook, A.B.; Peltier, R.; Zhang, J.; Gurnani, P.; Tanaka, J.;Burns, J.A.; Dallman, R.; Hartlieb, M.; Perrier, S., Hyperbranched poly(ethylenimine-co-oxazoline) by thiol-yne chemistry for non-viral gene delivery: investigating the role of polymer architecture, Polymer Chemistry, 2019 Advance article, DOI: 10.1039/C8PY01648H

196. Bray, C; Gurnani, P; Mansfield, E.D.H.; Peltier, R.; Perrier, S., Sulfonated Copolymers as Heparin-Mimickin Stabilizer of Fibroblast Growth Factor: Size, Architecture, and Monomer Distribution Effects, Biomacromolecules 2019 20 (1), pp 285 - 293 DOI: 10.1021/acs.biomac.8b01451

195 Cook, A.B.; Peltier, R.; Barlow, T.R.; Tanaka, J.; Burns, J.A.; Perrier, S Branched poly (trimethylphosphonium ethylacrylate-co-PEGA) by RAFT: alternative to cationic polyammoniums for nucleic acid complexation Journal of Interdisciplinary Nanomedicine 2018 doi: 10.1002/jin2.50

194. Brendel, J.C.; Sanchis, J.; Catrouillet, S.; Czuba, E.; Chen, M.Z.; Long, B.M.; Nowell, C.; Johnston, A.; Jolliffe, K.A.; Perrier, S. Secondary Self‐Assembly of Supramolecular Nanotubes into Tubisomes and Their Activity on Cells Angewandte Chemie 2018 DOI 10.1002/ange.201808543

193. Peltier, R.; Bialek, A.; Kuroki, A.; Bray, C.; Martin, L.; Perrier, S. Reverse-phase high performance liquid chromatography (RP-HPLC) as a powerful tool to characterise complex water-soluble copolymer architectures, Polymer Chemistry 2018 DOI: 10.1039/C8PY00966J

192. Shaikh, H.; Rho, J.Y.; Macdougall, L.J.; Gurnanin, P.; Lunn, A.M.; Yang, J.; Huband, S Mansfield, E.D.H.; Peltier, R.; Perrier, S. Hydrogel and Organogel Formation via Hierarchical Self-Assembly of Cyclic Peptides Nanotubes Chemistry - a European Journal 2018, DOI:

191. Morgan, T.E.; Ellacott, S.H.; Wootton, C.A.; Barrow, M.P.; Bristow, A.W.T.; Perrier, S; O’Connor, P.B.O., Coupling Electron Capture Dissociation and the Modified Kendrick Mass Defect for Sequencing of a Poly(2-ethyl-2-oxazoline) Polymer, Analytical Chemistry, 2018, DOI: 10.1021/acs.analchem.8b03591

190. Zhou, D; Kuchel, R.P.; Dong, S; Lucien, F.P.; Perrier, S; Zetterlund, P.B. Polymerization-Induced Self-Assembly Under Compressed CO2: Control of Morphology Using a CO2-Responsive MacroRAFT Agent, Macromolecular Rapid Communications, 2018, DOI: 10.1002/marc.201800335

189. Gurnani, P; Sanchez-Cano, C; Abraham, K; Xandri-Monje, H; Cook, A.B.; Hartlieb, M; Lévi, F; Dallmann, R and Perrier, S RAFT emulsion polymerisation as a platform to generate well-defined biocompatible latex nanoparticles.Macromolecular Bioscience 2018, DOI: 10.1002/mabi.201800213

188. Mansfield, E.D.H.; Hartlieb, M; Catrouillet, S; Rho, J.Y.; Larnaudie, S.C.; Rogers, S.E.; Sanchis, J; Brendel, J.C.; Perrier, S, Systematic study of the structural parameters affecting the self-assembly of cyclic peptide–poly(ethylene glycol) conjugates, Soft Matter, 2018,14, 6320-6326, DOI:10.1039/C8SM01133H

187. Cook, A.B.; Peltier, R; Hartlieb, M; Whitfield, R; Moriceau, G; Burns, J.A.; Haddleton, D.M; and Perrier, S Cationic and hydrolysable branched polymers by RAFT for complexation and controlled release of dsRNA, Polym. Chem., 2018,9, 4025-4035 DOI:10.1039/C8PY00804C

186. Gurnani, P; Bray, C.P.; Richardson. R.A.E.; Peltier, R; Perrier, S; Heparin‐Mimicking Sulfonated Polymer Nanoparticles via RAFT Polymerization‐Induced Self‐Assembly, Macromol. Rapid Commun. 2018, 1800314.

185. Whitfield, R; Anastasaki. A; Truong, N.P.; Cook, A.B.; Omedes-Pujol, M; Loczenski Rose, V; Nguyen, T.A.H.; Burns, J.A.; Perrier, S; Davis, T.P.; and Haddleton D.M Efficient Binding, Protection, and Self-Release of dsRNA in Soil by Linear and Star Cationic Polymers ACS Macro Lett., 2018, 7, pp 909–915 DOI: 10.1021/acsmacrolett.8b00420

184. Yasarapudi, V.B.;Frazer, L; Davis, N.J.L.K.; Booker, E.P.; Macmillan, A; Gallaher, J.K.;Roberts, D; Perrier, S; Schmidta, T.W Optimization of energy transfer in a polymer composite with perylene chromophores J. Mater. Chem. C, 2018, 6, 7333-7342 DOI:10.1039/C8TC02457J

183. Martin, L; Peltier, R; Kuroki, A; Town, J; Perrier, S, Investigating the Cell-Uptake of Guanidinium-Rich RAFT Polymers: Impact of Comonomer and Monomer Distribution Biomacromolecules 2018 DOI: 10.1021/acs.biomac.8b00146

182. Lunn, A.M; Perrier, S, Synthesis of Sub-100 nm Glycosylated Nanoparticles via a One Step, Free Radical, and Surfactant Free Emulsion Polymerization Macromolecular Rapid Communications 2018 DOI: 10.1002/marc.201800122

181. Larnaudie, S.C.; Sanchis, J; Nguyen, T; Peltier, R; Catrouillet, S; Brendel, J.C.; Porter, C.J.H.; Jolliffe, K.A.; Perrier, S Cyclic peptide-poly(HPMA) nanotubes as drug delivery vectors: In vitro assessment, pharmacokinetics and biodistribution Biomaterials, 2018, DOI: 

180. Binfield, J.G.; Brendel, J.C.; Cameron, N.R.; Eissa, A.M.; Perrier, S. Imaging Proton Transport in Giant Vesicles through Cyclic Peptide–Polymer Conjugate Nanotube Transmembrane Ion Channels Macromol. Rapid Commun. 2018, 1700831.

179. Larnaudie, S.C.; Brendel, J.C.; Romero-Canelón, I; Sanchez-Cano, C; Catrouillet, S; Sanchis, J; Coverdale, J.P.C; Song, J; Habtemariam, A; Sadler, P.J; Jolliffe, K.A.; Perrier, S. Cyclic Peptide–Polymer Nanotubes as Efficient and Highly Potent Drug Delivery Systems for Organometallic Anticancer Complexes, Biomacromolecules, 2018, 19 (1), pp 239–247 DOI: 10.1021/acs.biomac.7b01491

178. Kuroki, A; Sangwan, P; Qu, Y; Peltier, R; Sanchez-Cano, C; Moat, J; Dowson, C.G; Williams, EGL; Locock, K.E.S; Hartlieb, M; Perrier, S Sequence Control as a Powerful Tool for Improving the Selectivity of Antimicrobial Polymers ACS Appl. Mater. Interfaces, 2017, 9 (46), pp 40117–40126 DOI: 10.1021/acsami.7b14996

177. Larnaudie, S.C.; Brendel, J.C.; Jolliffe, K.A.; Perrier, S. pH-Responsive, Amphiphilic Core–Shell Supramolecular Polymer Brushes from Cyclic Peptide–Polymer Conjugates, ACS Macro Lett., 2017, DOI: 10.1021/acsmacrolett.7b00728

176. Rho, J.Y.; Brendel, J.C.; MacFarlane, L.R.; Mansfield, E.D.H.; Peltier, R.; Rogers, S.; Hartlieb, M.; Perrier, S. Probing the Dynamic Nature of Self-Assembling Cyclic Peptide–Polymer Nanotubes in Solution and in Mammalian Cells, Adv. Funct. Mater. 2017, 1704569 DOI: 10.1002/adfm.201704569

175. Kerr, A.; Hartlieb, M.; Sanchis, J.; Smith, T.; Perrier, S. Complex multiblock bottle-brush architectures by RAFT polymerization Chem. Commun., 2017, 53, 11901 - 11904

174. Brendel, J.C.; Martin, L.; Zhang, J.; Perier, S. SuFEx - A selectively triggered chemistry for fast, efficient and equimolar polymer-polymer coupling reactions, Polym. Chem., 2017, DOI: 10.1039/C7PY01636K

173. Perrier, S. RAFT Polymerization - A User Guide, Macromolecules, 2017, DOI: 10.1021/acs.macromol.7b00767

172. Zhang, J.; Deubler, R.; Hartlieb, M.; Martin, L.; Tanaka, J.; Patyukova, E.; Topham, P.D.; Schacher, F.H.; Perrier, S. Evolution of microphase separation with variations of segments of sequence-controlled multiblock copolymers, Macromolecules, 2017, DOI: 10.1021/acs.macromol.7b01831

171. Bray, C.; Peltier, R.; Kim, H.; Mastrangelo, A.; Perrier, S. Anionic Multiblock Core Cross-Linked Star Copolymers via RAFT Polymerization, Polym. Chem., 2017, DOI: 10.1039/C7PY01062A

170. Claus, T.K.; Zhang, J.; Martin, L.; Hartlieb, M.; Mutlu, H.; Perrier, S.; Delaittre, G.; Barner-Kowollik, C. Stepwise light-induced dual compaction of single-chain nanoparticles, Macromol. Rapid Commun. 2017, Volume: 38 Issue: 16, DOI: 10.1002/marc.201700264

169. Silk, M.R.; Newman, J.; Ratcliffe, J.C.; White, J.F.; Caradoc-Davies, T.; Price, J.R.; Perrier, S.; Thompson, P.E.; Chalmers, D.K. Parallel and Antiparallel Cyclic D/L Peptide Nanotubes, Chem. Commun. 2017, 49, 6613-6616 DOI: 10.1039/c7cc00846e

168. Moriceau, G.; Gody, G.; Hartlieb, M.; Winn, J.; Kim, H.; Mastrangelo, A.; Smith, T.; Perrier S Functional Multisite Copolymer by One-Pot Sequential RAFT Copolymerization of Styrene and Maleic Anhydride Polym. Chem., 2017, 4152 – 4161 DOI: 10.1039/C7PY00787F

166. Kuroki, A.; Martinez-Botella, I.; Hornung, C.H.; Martin, L.; Williams, E.G.L.; Locock, K.E.S.; Hartlieb, M.; Perrier, S. Looped flow RAFT polymerization for multiblock copolymer synthesis Polym. Chem., 2017, 8, 3249-3254 DOI: 10.1039/C7PY00630F

165. Joubert, F.; Martin, S.; Perrier, S.; Pasparakis, G. Development of a Gemcitabine-Polymer Conjugate with Prolonged Cytotoxicity against a Pancreatic Cancer Cell Line, ACS Macro. Lett., 2017, DOI: 10.1021/acsmacrolett.7b00160

164. Tanaka, J.; Gleinich, A.S.; Zhang, Q.; Whitfield, R.; Kempe, K.; Haddleton, D.M.; Davis, T.P.; Perrier, S.; Mitchell, D.A.; Wilson, P. Specific and differential binding of N-acetylgalactosamine glycopolymers to the human Macrophage Galactose Lectin and Asialoglycoprotein Receptor, Biomacromolecules, 2017, 18 (5), 1624-1633, DOI: 10.1021/acs.biomac.7b00228

163. Zhou, D.; Dong, S.; Kuchel, R.P.; Perrier, S. Zetterlund, P.B. Polymerization Induced Self-Assembly: Tuning of Morphology using Ionic Strength and pH, Polym. Chem. 2017, 8, 3082-3089 DOI: 10.1039/C7PY00552K

162. Hartlieb M.; Williams E.G.; Kuroki A.; Perrier S.; Locock K.E. Antimicrobial polymers: Mimicking amino acid functionality, sequence control and three-dimensional structure of host-defense peptides, Curr. Med. Chem., 2017, DOI: 10.2174/0929867324666170116122322

161. Hartlieb, M.; Floyd, T.; Cook, A.B.; Sanchez-Cano, C.; Catrouillet, S.; Burns, J.; Perrier, S. Well-defined hyperstar copolymers based on a thiol-yne hyperbranched core and a poly(2-oxazoline) shell for biomedical applications, Polym. Chem., 2017, 8, 2041-2054. DOI: 10.1039/C7PY00303J

160. Moraes, J.; Peltier, R.; Gody, G.; Blum, M.; Recalcati, S.; Klok, H.-H.; Perrier, S. Influence of block versus random monomer distribution on the cellular uptake of hydrophilic copolymers, ACS Macro Lett., 2016, 5 (12), 1416-1420, DOI: 10.1021/acsmacrolett.6b00652

159. Zhang, J.; Gody, G.; Hartlieb, M.; Catrouillet, S.; Moffat, J.; Perrier, S. Synthesis of Sequence-Controlled Multi-block Single Chain Nanoparticles by a Step-wise Folding-Chain Extension-Folding Process, Macromolecules, 2016, 49 (23), 8933–8942, DOI: 10.1021/acs.macromol.6b01962

158. Poon, C.K.; Tang, O.; Chen, X.-C.; Kim, B.; Hartlieb, M.; Pollock, C.A.; Hawkett, B.S.; Perrier, S Fluorescent labelling and biodistribution of latex nanoparticles formed by surfactant-free RAFT emulsion polymerisation, Macromol. Biosci. 2016, DOI: 10.1002/mabi.201600366 Accepted 21/10/16

157. Koh, M. K.; FitzGerald, P. A.; Warr, G. G.; Jolliffe, K. A; Perrier, S. Study of (cyclic peptide)-polymer conjugate assemblies by small angle neutron scattering, Chem. Eur. J. 2016, DOI: 10.1002/chem.201603091

156. Isahak, N.; Gody, G.; Malins, L. R.; Mitchell, N. J.; Payne, R. J.; Perrier, S. Single Addition of an Allyl Amine Monomer Enables Access to End-Functionalized RAFT Polymers for Native Chemical Ligation, Chem. Commun. 2016, 52, 12952-12955. DOI: 10.1039/C6CC06010B

155. Catrouillet, S.; Brendel, J.; Larnaudie, S.; Barlow, T.; Jolliffe, K.; Perrier, S. Tunable length of cyclic peptide-polymer conjugate self-assemblies in water, ACS Macro Lett., 2016, 5 (10), 1119–1123 DOI: 10.1021/acsmacrolett.6b00586

154. Tom, J.; Ohno, K.; Perrrier, S. Surface-Initiated SET Living Radical Polymerisation for the Synthesis of Silica–Polymer Core–Shell Nanoparticles, Polym Chem, 2016, 7, 6075-6083 DOI: 10.1039/C6PY01290F.

153.Gurnani, P.; Lunn, A.; Perrier, S. Synthesis of mannosylated and PEGylated nanoparticles via RAFT emulsion polymerisation, and investigation of particle-lectin aggregation using turbidimetric and DLS techniques, Polymer, 2016, 106, 229-237 DOI: 10.1016/j.polymer.2016.08.093

152. Barlow, T.; Brendel, J.; Perrier, S, Poly(bromoethyl acrylate): A reactive precursor for the synthesis of functional RAFT materials, Macromolecules, 2016, 49 (17), 6203–6212 DOI: 10.1021/acs.macromol.6b00721

151. Davis, N. J. L. K.; MacQueen, R.W.; Roberts, D.A.; Danos, A.; Dehn, S.; Perrier, S.; Schmidt. T.W. Energy Transfer in Pendant Perylene Diimide Copolymers, J. Mater. Chem. C, 2016, 4, 8270-8275, DOI: 10.1039/C6TC02555B

150. Brendel, J. C.; Gody, G.; Perrier, S. Efficient click-addition sequence for polymer-polymer couplings, Polym. Chem. 2016, ,7, 5536-5543, DOI: 10.1039/C6PY00954A

149. Isahak, N.; Sanchez, J.; Perrier, S.; Stone, M.J.; Payne, R.J. Synthesis of polymers and nanoparticles bearing polystyrene sulfonate brushes for chemokine binding, Org. Biomol. Chem. 2016, 14, 5652-5658, DOI: 10.1039/C6OB00270F

148. Gody, G; Roberts, D A; Maschmeyer, T; and Perrier, S, A New Methodology for Assessing Macromolecular Click Reactions and Its Application to Amine-Tertiary Isocyanate Coupling for Polymer Ligation, J. Am. Chem. Soc., 2016, 138 (12), pp 4061–4068

147. Poon, CK; Tang, O; Chen, ; Pham, BTT; Gody, G; Pollock, CA; Hawkett, BS; Perrier, S Preparation of Inert Polystyrene Latex Particles as MicroRNA Delivery Vectors by Surfactant-Free RAFT Emulsion Polymerization Biomacromolecules 2016, 3, 965-973

146 Cook, AB; Barbey, R ; Burns, JA ; Perrier, S; Hyperbranched Polymers with High Degrees of Branching and Low Dispersity Values: Pushing the Limits of Thiol-Yne Chemistry, Macromolecules. 2016 4,1296-1304

145 Gody, G.; Zetterlund, P.B.; Perrier, S.; Harrisson, S. The limits of precision monomer placement in chain growth polymerization, Nat. Commun. 2016, 10.1038/ncomms10514

144 Sabouri, H.; Ohno, K.; Perrier, S. Silica Core - Polystyrene Shell Nanoparticles Synthesis and Assembly in Three Dimensions, Nanoscale, 2015, 7, 19036-19046

143 Larnaudie, S.C; Brendel, J.C.; Jolliffe, K.A.; Perrier, S. Cyclic peptide-polymer conjugates: grafting to VS grafting from, J. Polym. Sci. Part A: Polym. Chem., 2015, 10.1002/pola.27937

142 Zetterlund, P.B.; Thickett, S.; Perrier, S.; Bourgeat-Lami, E.; Lansalot, M. Controlled/Living Radical Polymerization in Dispersed Systems: Theory and Applications, Chem. Rev., 2015, 115 (18), 9745-9800

141 Kolomanska, J.; Johnston, P.; Gregori, A.; Fraga Dominguez, I.; Perrier, S.; Rivaton, A.; Dagron-Lartigau, C.; Topham, P.D. Design, synthesis and thermal behaviour of a series of well-defined clickable and triggerable sulfonate polymers, RSC Advances, 2015, 5, 66554-66562.

140 Sabouri, H.; Ohno, K.; Perrier, S. Well-Defined Colloidal Crystal Films from the 2D Self-Assembly of Core–Shell Semi-Soft Nanoparticles, Polym. Chem., 2015, 7297-7307

139 Martin, L.; Gody, G.; Perrier, S. Preparation of Complex Multiblock Copolymers via Aqueous RAFT Polymerization at Room Temperature, Polym. Chem., 2015, 4875-4886. Cover article. Highlighted paper of the month in Polym Chem, July 2015.

Aqueous MultiBlock cover


138 Dong, S.; Zhao, W.; Lucien, F.P.; Perrier, S.; Zetterlund, P.B. Polymerization Induced Self-Assembly: Tuning of Nano-Object Morphology by Use of CO2, Polym. Chem., 2015, 2249-2254

137 Gody, G.; Danial, M.; Barbey, R.; Perrier, S. Ultrafast RAFT Polymerization: Multiblock Copolymers within Minutes, Polym. Chem., 2015, 6, 1502-1511

136 Cobo, I.; Li, M.; Sumerlin, B. S.; Perrier, S. Smart hybrid materials by conjugation of responsive polymers to biomacromolecules, Nature Mat. 2015, 14 (2), 143-159

135 Danial, M.; Perrier, S.; Jolliffe, K.A. Effect of the amino acid composition of cyclic peptides on their self-assembly in lipid bilayers Organic & Biomolecular Chemistry, 2015, 13, 2464-2473.

134 Moraes, J.; Ohno, K.; Maschmeyer, T.; Perrier, S., Selective Patterning of Gold Surfaces by Core-Shell, Semi-Soft Hybrid Nanoparticles, Small 2015, 11 (4), 482-488

133 Pace, S.; Vasani, R.B.; Zhao, W.; Perrier, S.; Voelcker, N.H. Photonic porous silicon as a pH sensor, Nanoscale Research Letters 2014, 9, 420

132 Koh, M. L.; Jolliffe, K. A., Perrier, S. Hierarchical Assembly of Branched Supramolecular Polymers from (Cyclic Peptide)–Polymer Conjugates, Biomacromolecules 2014, 15 (11), 4002-4011

131 Barbey, R.; Perrier, S. Synthesis of Polystyrene-Based Hyperbranched Polymers by Thiol–Yne Chemistry: A Detailed Investigation, Macromolecules 2014, 47 (19), 6697-6705

130 Blunden, B. M.; Chapman, R.; Danial, M.; Lu, H.; Jolliffe, K. A.; Perrier, S.; Stenzel, M.H. Drug conjugation to cyclic peptide-polymer self-assembling nanotubes, Chem. Eur. J. 2014, 20 (40), 12745-12749

129 Zhao, W.; Gody, G.; Dong, S.; Zetterlund, P.B.; Perrier, S. Optimization of the RAFT Polymerization Conditions for the in Situ Formation of Nano-objects via Dispersion Polymerization in Alcoholic Medium, Polym. Chem. 2014, 5 (24), 6990-7003.

128 FitzGerald, P.A.; Gupta, S.; Wood, K.; Perrier, S.; Warr, G.G. Temperature and pH responsive micelles with collapsible poly(N-isopropylacrylamide) head groups, Lagmuir 2014, DOI: 10.1021/la501861t

127 Danial, M.; My-Nhi Tran, C.; Jolliffe, K.A. Perrier, S. Thermal Gating in Lipid Membranes Using Thermoresponsive Cyclic PeptidePolymer Conjugates, J. Am. Chem. Soc. 2014, DOI: 10.1021/ja5024699

126 Gody, G.; Maschmeyer, T.; Zetterlund, P.B.; Perrier, S. Pushing the Limit of the RAFT Process: Multiblock Copolymers by One-Pot Rapid Multiple Chain Extensions at Full Monomer Conversion, Macromolecules 2014, DOI: 10.1021/ma402435n

125 Le-Masurier, S.P.; G. Gody, G.; Perrier, S.; Granville, A.M. One-pot polymer brush synthesis via simultaneous isocyanate coupling chemistry and “grafting from” RAFT polymerization, Polym. Chem. 2014, DOI: 10.1039/C4PY00025K.

124 Zetterlund, P.B.; Gody, G.; Perrier, S. Sequence-Controlled Multiblock Copolymers via RAFT Polymerization: Modeling and Simulations, Macromol. Theory Simul. 2014, DOI: 10.1002/mats.201300165

123 Gody, G.; Maschmeyer, T.; Zetterlund, P.B.; Perrier, S. Exploitation of the Degenerative Transfer Mechanism in RAFT Polymerization for Synthesis of Polymer of High Livingness at Full Monomer Conversion, Macromolecules, 2014, DOI: 10.1021/ma402286e

122 Roberts, D. A.; Crossley, M. J.; Perrier, S. Fluorescent Bowl-shaped Nanoparticles from ‘Clicked’ Porphyrin-Polymer Conjugates, Polym. Chem. 2014, 2014, 5 (13), 4016 – 4021.

121 Tischer, T.; Claus, T.; Bruns, M.; Trouillet, V.; Linkert, K.; Rodriguez-Emmenegger, C.; Goldmann, A.; Perrier, S.; Börner, H.; Barner-Kowollik, C. Spatially Controlled Photochemical Peptide and Polymer Conjugation on Biosurfaces, Biomacromolecules, 2013, 14(12), 4340–4350.

120 Danial, M.; My-Nhi Tran, C.; Young, P.G.; Perrier, S.; Jolliffe, K.A. Janus cyclic peptide–polymer nanotubes Nat. Commun., 2013, 4:2780 DOI: 10.1038/ncomms3780. Highlighted in the scientific press: Science Newsline, Sciences Daily, e! Science News, EurkAlert!, Nanowerk,,

119 Coleman, R.; Jack, K.; Perrier, S.; Grondahl, L. Hydroxyapatite Mineralization in the Presence of Anionic Polymers, Cryst. Growth Des., 2013, 13(10), 4252–4259.

118 Roberts, D. A.; Crossley, M. J.; Schmidt, T. W.; Perrier, S. Tunable Self-Assembly of Triazole–Linked Porphyrin–Polymer Conjugates, Chem. Eur. J., 2013, 19(38), 12759-12770. Highlighted in ‘ChemViews’ (

117 Gody, G.; Maschmeyer, T.; Zetterlund, P.B.; Perrier, S. Rapid and Quantitative One-Pot Synthesis of Sequence-Controlled Polymers by Radical Polymerization, Nat. Commun., 2013, 4:2505 DOI: 10.1038/ncomms3505. Highlighted in Nature Chem, News & Views, Dec 2013, 5 (12), 990.

116 Moraes, J.; Ohno, K.; Maschmeyer, T.; Perrier, S. Synthesis of Silica-Polymer Core-Shell Nanoparticles by Reversible Addition-Fragmentation Chain Transfer Polymerization, Chem. Commun., 2013, 49 (80), 9077 – 9088. Cover article


115 Moraes, J.; Ohno, K.; Maschmeyer, T.; Perrier, S. Monodisperse, Charge-Stabilized, Core–Shell Particles via Silica-Supported Reversible Addition–Fragmentation Chain Transfer Polymerization for Cell Imaging, Chem. Mater., 2013, 25 (17), 3522–3527

114 Cao, S.; Gody, G.; Zhao, W.; Perrier, S.; Peng, X.; Ducati, C.; Zhao Z.; Cheetham, A.K. Hierarchical bicontinuous porosity in metal–organic frameworks templated from functional block co-oligomer micelles, Chem. Sci., 2013, 4 (9), 3573 – 3577.

113 Siauw, M.; FitzGerald, P. A.; Hawkett, B. S.; Perrier, S. Thermoresponsive behavior of amphiphilic diblock co-oligomers of ethylene glycol and styrene in
aqueous solution, Soft Matter, 2013, 9 (29), 7007 – 7015. Special Issue on ‘Emerging Investigators’

112 Moraes, J.; Ohno, K.; Gody, G.; Maschmeyer, T.; Perrier, S. The synthesis of well-defined poly(vinylbenzyl chloride)-grafted nanoparticles via RAFT polymerization, Beilstein J. Org. Chem., 2013, 9, 1226-1234.

111 Chapman, R.; Bouten, P. J. M.; Hoogenboom, R.; Jolliffe, K. A.; Perrier, S. Thermoresponsive cyclic peptide – poly(2-ethyl-2- oxazoline) conjugate nanotubes, Chem. Commun., 2013, 49 (58), 6522 - 6524.

110 Barbey, R.; Perrier, S. Facile Route to Functional Hyperbranched Polymers by Combining Reversible Addition−Fragmentation Chain Transfer Polymerization, Thiol−Yne Chemistry, and Postpolymerization Modification Strategies, ACS Macro Lett., 2013, 2 (5), 366-370. Top Most Read Articles for Q2 2013 for ACS Macro Letters

109 Chapman, R.; Koh, M.L.; Warr, G.G; Jolliffe, K.A.; Perrier, S. Structure elucidation and control of cyclic peptide-derived nanotube assemblies in solution, Chem. Sci., 2013, 4 (6), 2581 - 2589

108 Chapman, R.; Warr, G.G; Jolliffe, K.A.; Perrier, S. Multi-Shell Soft Nanotubes from Cyclic Peptide Templates, Adv. Mater., 2013, 25, 1170–1172.

107 Zhao, W.; Fonsny, P.; FitzGerald, P.; Warr, G.G.; Perrier, S. Unexpected Behavior of Polydimethylsiloxane / Poly(2-(dimethylamino)ethyl acrylate) (Charged) Amphiphilic Block Copolymers in Aqueous Solution, Polym. Chem., 2013, 4(6), 2140-2150.

106 Chapman, R.; Warr, G.G; Perrier, S.; Jolliffe, K.A. Water Soluble and pH-Responsive Polymeric Nanotubes from Cyclic Peptide Templates, Chem. Eur. J., 2013, 19, 1955-1961.

105 Lim, S. K.; Perrier, S.; Neto, C. Patterned chemisorption of proteins by thin
polymer film dewetting, Soft Matter, 2013, 9 (9), 2598-2602.

104 Wilkinson, B.L.; Day, S.; Chapman, R.; Perrier, S.; Apostolopoulos, V.; Payne, R.J. Synthesis and Immunological Evaluation of Self-Assembling and Self-Adjuvanting Tri-Component Glycopeptide Cancer Vaccine Candidates, Chem. Eur. J., 2012, 18(51), 16540-16548.

103 Semsarilar, M.; Tom, J.; Ladmiral, V.; Perrier, S. Supramolecular Hybrids of Cellulose and Synthetic Polymers, Polym. Chem., 2012, 3(12), 3266-3275.

102 Wei, H.; Perrier, S.; Dehn, S.; Ravarian, R.; Dehghani, F. One-pot ATRP synthesis of PEG-b-PNIPAAm-b-P(NIPAAm-co-HEAAm) triblock copolymer with dual LCSTs and its thermo-induced association behaviour, Soft Matter, 2012, 8, 9526–9528.

101 Sugihara, Y.; Semsarilar, M.; Perrier, S.; Zetterlund, P.B. Assessment of the influence of microwave irradiation on
conventional and RAFT radical polymerization of styrene, Polym. Chem., 2012, 3(12), 2801-2806.

100 Dehn, S.; Castelletto, V. ; Hamley, I. W. ; Perrier, S. Altering Peptide Fibrillisation by Polymer Conjugation Biomacromolecules, 2012, 13 (9), 2739–2747.

99 Chapman, R.; Danial, M.; Koh, M. L.; Jolliffe, K. A. Perrier, S. Design and properties of functional nanotubes from the self-assembly of cyclic peptide templates, Chem. Soc. Rev., 2012, 41 (18), 6023 – 6041.

98 Gody, G.; Rossner, C.; Moraes, J.; Vana, P.; Maschmeyer, T. ; Perrier, S. One-pot RAFT/“click” chemistry via isocyanates: Efficient synthesis of α-end-functionalized polymers, J. Am. Chem. Soc., 2012, 134 (30), 12596–12603. Highlighted in ‘Chemistry in Australia’, October 2012

97 Poon C. K.; Chapman, R.; Jolliffe, K. A.; Perrier, S. Pushing the limits of copper mediated azide-alkyne cycloaddition (CuAAC) to conjugate polymeric chains to cyclic peptides, Polym. Chem., 2012, 3 (7), 1820-1826.

96 Siauw, M.; Hawkett, B.S.; Perrier, S. Short Chain Amphiphilic Diblock Co-Oligomers via RAFT Polymerization, J. Polym. Sci., Part A: Polym. Chem., 2012, 50 (1), 187-198.

95 Ohno, K.; Ma, Y.; Huang, Y.; Mori, C.; Yahata, Y.; Tsujii, Y.; Maschmeyer, T.; Moraes, J.; Perrier, S.; Surface-Initiated Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization from Fine Particles Functionalized with Trithiocarbonates, Macromolecules, 2011, 44 (22), 8944-8953.

94 West, A.; Hornby, B.; Tom, J.; Ladmiral, V.; Harrisson, S.; Perrier, S. Origin of Initial Uncontrolled Polymerization and its Suppression in the Copper-(0)-mediated Living Radical Polymerization of Methyl Acrylate, Macromolecules, 2011, 44 (20), 8034-8041.

93 Konkolewicz, D.; Perrier, S.; Stapleton, D.; Gray-Weale, A. Modelling Highly Branched Structures: Description of the solution structures of dendrimers, polyglycerol, and glycogen, J. Polym. Sci, Part B: Polym. Phys., 2011, 49 (21), 1525-1538.

92 Konkolewicz, D.; Monteiro, M. J.; Perrier, S. Dendritic and Hyperbranched Polymers from Macromolecular Units: Elegant approaches to the synthesis of functional polymers, Macromolecules, 2011, 44 (18), 7067-7087. Top Most Read Articles for Q3 2011 for Macromolecules


91 Bell, C. A.; Jia, Z.; Perrier, S. Monteiro, M. J. Modulating Catalytic Activity of Polymer-Based CuAAC ‘‘click’’ Reactions, J. Polym. Sci., Part A: Polym. Chem., 2011, 49 (21), 4539-4548.

90 Moraes, J.; Maschmeyer, T.; Perrier, S. ‘Pseudo-star’ Copolymers Formed by a Combination of RAFT Polymerization and Isocyanate-Coupling, Aust. J. Chem., 2011, 64, 1-7. Cover Article


89 Chapman, R.; Jolliffe, K.A.; Perrier, S. Modular Design for the Controlled Production of Polymeric Nanotubes from Polymer/Peptide Conjugates, Polym. Chem., 2011, 2 (9), 1956-1963. Cover article


88 Moraes, J.; Maschmeyer, T.; Perrier, S. “Clickable” Polymers via a Combination of RAFT Polymerization and Isocyanate Chemistry, J. Polym. Sci., Part A: Polym. Chem., 2011, 49 (13), 271-2782.

87 Dehn, S.; Chapman, R.; Jolliffe, K. A.; Perrier, S. Synthetic Strategies for the Design of Peptide / Polymer Conjugates, Polym. Rev., 2011, 51(02), 214-234.

86 Koh, M.L.; Konkolewicz, D.; Perrier, S. A Simple Route to Functional Highly Branched Structures: The RAFT Homopolymerization of Divinylbenzene, Macromolecules, 2011, 44 (8), 2715–2724.

85 Zhao, Y.; Zhang, C.; Zhou, Y.; Liu, Q.; Li, S.; Perrier, S. Facile Synthesis of Hyperbranched and Star-Shaped Polymers by RAFT Polymerization Based on a Polymerizable Trithiocarbonate, Macromolecules, 2011, 44 (7), 2034–2049.

84 Wei, H.; Ravarian, R.; Dehn, S.; Perrier, S.; Dehghani, F. Construction of Temperature Responsive Hybrid Crosslinked Self-Assemblies Based on PEG-b-P(MMA-co-MPMA)-b-PNIPAAm Triblock Copolymer: ATRP Synthesis and Thermoinduced Association Behavior, J. Polym. Sci., Part A: Polym. Chem., 2011, 49 (8), 1809-1820.

83 Konkolewicz, D.; Gaillard, S.; West, A.G.; Cheng, Y.Y; Gray-Weale, A.; Schmidt, T.W., Nolan, S.P.; Perrier, S. Luminescent Hyperbranched Polymers: Combining Thiol-Yne Chemistry with Gold-Mediated C-H Bond Activation, Organometallics, 2011, 30 (6), 1315-1318.

82 Kakwere, H.; Payne, R.J.; Jolliffe. K.A.; Perrier, S. Self assembling macromolecular chimeras: Controlling fibrillization of a b-sheet forming peptide by polymer conjugation, Soft Matter, 2011, 7, 3754–3757.

81 Zetterlund, P.B.; Perrier, S. RAFT Polymerization under Microwave Irradiation: Toward Mechanistic Understanding, Macromolecules, 2011, 44, 1340–1346.

80 Konkolewicz, D.; Poon, C. K.; Gray-Weale, A.; Perrier, S. Hyperbranched Alternating Block Copolymers using Thiol-Yne Chemistry: Materials with Tuneable Properties, Chem. Commun., 2011, 47, 239-241.

79 Kakwere, H.; Perrier, S. Design of complex polymeric architectures and nanostructured materials/hybrids by living radical polymerization of hydroxylated monomers, Polym. Chem., 2011, 2, 270-288. Top Ten most-read Polymer Chemistry articles when published on-line (August 2010)

78 Khaydarov, A.A.; Kazlauciunas, A.; Mounterey, P.E.; Perrier, S. Investigation of polymer blends polyamide-6 with polymethylmethacrylate syntheses by RAFT polymerization. Polym. Bull., 2010, 66 (8), 1089-1098.

77 O’Driscoll, B.M.D.; Griffiths, G.H.; Matsen, M.W.; Perrier, S.; Ladmiral, V.; Hamley, I.W. Lateral Phase Separation in Grafted Diblock Copolymer Films, Macromolecules, 2010, 43 (19), 8177–8184.

76 Huang, Y.; Hou, T.; Cao, X.; Perrier, S.; Zhao, Y. Synthesis of silica-polymer hybrids by combination of RAFT polymerization and azide-alkyne cycloaddition ‘click’ reaction, Polym. Chem., 2010, 1 (10), 1615-1623.

75 Semsarilar, M.; Perrier, S. ‘Green’ Reversible Addition-Fragmentation Chain-Transfer (RAFT) Polymerization, Nature Chem, 2010, 2, 811-820.

74 Konkolewicz, D.; Gray-Weale, A.; Perrier, S. Describing the structure of a randomly hyperbranched polymers, Macromol. Theo. Simul., 2010, 19, 219-227.

73 Semsarilar, M.; Ladmiral, V.; Perrier, S. Synthesis of a cellulose supported chain transfer agent and its application to RAFT polymerization, J. Polym. Sci., Part A: Polym. Chem., 2010, 48, 4361–4365.

72 West, A.; Barner-Kowollik, C.; Perrier, S. Poly(ethylene glycol) as a ‘green solvent’ for the RAFT polymerization of methyl methacrylate, Polymer, 2010, 51, 3836-3842.

71 Chapman, R.; Jolliffe, K.A; Perrier, S. Synthesis of self assembling cyclic peptide-polymer conjugates using click chemistry, Aust. J. Chem., 2010, 63, 1169-1172.

70 Konkolewicz, D.; Gray-Weale, A.; Perrier, S. The Structure of Randomly Branched Polymers Synthesized by Living Radical Methods, Polym. Chem., 2010, 1, 1067-1077.

69 Hornby, B.; West, A.; Tom, J.; Waterson, C.; Harrisson, S.; Perrier, S. Copper(0)-mediated living radical polymerisation of methyl methacrylate in a non-polar solvent. Macromol. Rapid Commun. 2010, 31 (14), 1276–1280.

68 Tom, J.; Hornby, B.; West, A.; Harrisson, S.; Perrier, S. Copper(0)-mediated living radical polymerization of styrene, Polym. Chem., 2010, 1, 420-422.

67 Kakwere, H.; K.Y. Chun, C.; Jolliffe. K.A.; Payne, R.J., Perrier, S. Polymer-peptide chimeras for the multivalent display of immunogenic peptides. Chem. Commun., 2010, 46, 2188-2190. Cover article.


66 Semsarilar, M.; Ladmiral, V.; Perrier, S. Highly branched and hyperbranched glycopolymers via reversible addition fragmentation chain transfer polymerization and click chemistry. Macromolecules, 2010, 43 (3), 1438–1443.

65 Sriprom, W.; Neto, C.; Perrier, S. Rapid photochromic nanopatterns from block copolymers. Soft Matter, 2010, 6, 909-914. Cover article.


64 Konkolewicz, D.; Gray-Weale, A.; Perrier, S. Hyperbranched polymers by thiol-yne chemistry, from small molecules to functional polymers. J. Am. Chem. Soc., 2009, 131 (50), 18075-18077.

63 Suchao-in, N.; Chirachanchai, S.; Perrier, S. Control of block copolymer morphology: an example of selective morphology induced by self- assembly formation condition. J. Polym. Sci., Part A: Polym. Chem., 2009, 47 (24), 6783-6788.

62 Brown, S. L.; Konkolewicz, D.; Gray-Weale, A.; Motherwell, W.B.; Perrier, S. Searching for Stars: Selective desulfurization and fluorescence spectroscopy as new tools in the search for cross-termination side-products in reversible addition fragmentation chain transfer (RAFT) polymerization. Aust. J. Chem., 2009, 62, 15333-1536.

61 Boyer, C.; Bulmus, V.; Davis, T.P.; Ladmiral, V.; Liu, J.; Perrier, S. Bio-applications of RAFT polymerization. Chem. Rev., 2009, 109 (11), 5402-5436.

60 Kakwere, H., Perrier, S. Facile synthesis of star–shaped copolymers via combination of RAFT and ring opening polymerization. J. Polym. Sci., Part A: Polym. Chem., 2009, 47 (23), 6396-6408.

59 Zhao, Y.; Perrier, S.; Zhou, X.; Huang, Y.; Liu, Q. Synthesis of silica particles grafted with well-defined living polymeric chains by combination of raft polymerization and coupling reaction. Macromolecules 2009, 42 (15), 5509-5517.

58 Suchao-in, N.; Chirachanchai, S.; Perrier, S. pH- and thermo- multi-responsive fluorescent micelles from block copolymers via reversible addition fragmentation chain transfer (raft) polymerization. Polymer 2009, 50 (17), 4151-4158.

57 Konkolewicz, D.; Hawkett, B. S.; Gray-Weale, A.; Perrier, S., RAFT polymerization kinetics: how long are the cross-terminating oligomers? J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 3455-3466.

56 Roy, D.; Semsarilar, M.; Guthrie, J.T.; Perrier, S. Cellulose modification by polymer grafting: A review. Chem. Soc. Rev. 2009, 38, 2046-2064. Cover Article.


55 Konkolewicz, D.; Siaw, M.; Hawkett, B. S.; Gray-Weale, A.; Perrier, S., Obtaining kinetic information from the chain-length distribution of polymers produced by RAFT. J. Phys. Chem B 2009, 113, (20), 7086–7094.

54 Sriprom, W.; James, M.; Perrier, S.; Neto, C., Ordered Microphase Separation in Thin Films of PMMA−PBA Synthesized by RAFT: Effect of Block Polydispersity, Macromolecules, 2009, 42, (8), 3138–3146.

53 Semsarilar, M.; Perrier, S., Solubilization and functionalization of cellulose assisted by microwave irradiation. Aust. J. Chem. 2009, 62, (3), 223-226.

52 Kakwere, H.; Perrier, S., Orthogonal “relay” reactions to design functional soft nanoparticles. J. Am. Chem. Soc. 2009, 131(5), 1889-1895. Highlighted in ‘Chemistry in Australia’, May 2009.

51 Nguyen, D. H.; Wood, M. R.; Zhao, Y.; Perrier, S.; Vana, P., Solid-supported MADIX polymerization of vinyl acetate. Macromolecules 2008, 41, (19), 7071-7078.

50 Lee, H.; Terry, E.; Zong, M.; Arrowsmith, N.; Perrier, S.; Thurecht, K. J.; Howdle, S. M., Successful dispersion polymerization in supercritical CO2 using polyvinylalkylate hydrocarbon surfactants synthesized and anchored via RAFT. J. Am. Chem. Soc. 2008, 130, (37), 12242-12243.

49 Ladmiral, V.; Legge, T. M.; Zhao, Y. L.; Perrier, S., "Click" chemistry and radical polymerization: Potential loss of orthogonality. Macromolecules 2008, 41, (18), 6728-6732. Featured in the Virtual Issue of Macromolecules, “Click Chemistry in Macromolecular Science”, May 28, 2009, Volume vi, Issue 1.

48 Konkolewicz, D.; Hawkett, B. S.; Gray-Weale, A.; Perrier, S., RAFT polymerization kinetics: Combination of apparently conflicting models. Macromolecules 2008, 41, (17), 6400-6412.

47 Barner-Kowollik, C.; Perrier, S., The future of reversible addition fragmentation chain transfer polymerization. J. Polym. Sci. Part A: Polym. Chem. 2008, 46, (17), 5715-5723. Cover Article. Ranked in the Top 20 most downloaded articles of this journal in 2008.


46 Achilleos, M.; Legge, T. M.; Perrier, S.; Patrickios, C. S., Poly(ethylene glycol)-Based Amphiphilic Model Conetworks: Synthesis by RAFT Polymerization and Characterization. J. Polym. Sci. Part A: Polym. Chem. 2008, 46, (22), 7556-7565.

45 Roy, D.; Knapp, J. S.; Guthrie, J. T.; Perrier, S., Antibacterial cellulose fiber via RAFT surface graft polymerization. Biomacromolecules 2008, 9, (1), 91-99.

44 Roy, D.; Guthrie, J. T.; Perrier, S., Synthesis of natural-synthetic hybrid materials from cellulose via the RAFT process. Soft Matter 2008, 4, (1), 145-155.

43 Zhao, Y.; Perrier, S., Synthesis of well-defined conjugated copolymers by RAFT polymerization using cysteine and glutathione-based chain transfer agents. Chem. Commun. 2007, (41), 4294-4296.

42 Zhao, Y.; Perrier, S., Reversible addition-fragmentation chain transfer graft polymerization mediated by fumed silica supported chain transfer agents. Macromolecules 2007, 40, (25), 9116-9124.

41 Wood, M. R.; Duncalf, D. J.; Findlay, P.; Rannard, S. P.; Perrier, S., Investigation of the experimental factors affecting the trithiocarbonate-mediated raft polymerization of methyl acrylate. Aust. J. Chem. 2007, 60, (10), 772-778.

40 Sriprom, W.; Neel, M.; Gabbutt, C. D.; Heron, B. M.; Perrier, S., Tuning the color switching of naphthopyrans via the control of polymeric architectures. J. Mater. Chem. 2007, 17, (19), 1885-1893.

39 Legge, T. M.; Slark, A. T.; Perrier, S., Novel difunctional reversible addition fragmentation chain transfer (RAFT) agent for the synthesis of telechelic and aba triblock methacrylate and acrylate copolymers. Macromolecules 2007, 40, (7), 2318-2326.

38 Khaydarov, A. A.; Hamley, I. W.; Legge, T. M.; Perrier, S., Surface structure of thin asymmetric PS-b-PMMA diblock copolymers investigated by atomic force microscopy. Eur. Polym. J. 2007, 43, (3), 789-796.

37 Jitchum, V.; Perrier, S., Living radical polymerization of isoprene via the RAFT process. Macromolecules 2007, 40, (5), 1408-1412.

36 Gemici, H.; Legge, T. M.; Whittaker, M.; Monteiro, M. J.; Perrier, S., Original approach to multiblock copolymers via reversible addition-fragmentation chain transfer polymerization. J. Polym. Sci., Part A: Polym. Chem. 2007, 45, (11), 2334-2340.

35 Brown, S. L.; Rayner, C. M.; Perrier, S., Microwave-accelerated RAFT polymerization of polar monomers. Macromol. Rapid Commun. 2007, 28, (4), 478-483.

34 Brown, S. L.; Rayner, C. M.; Graham, S.; Cooper, A.; Rannard, S.; Perrier, S., Ultra-fast microwave enhanced reversible addition-fragmentation chain transfer (RAFT) polymerization: monomers to polymers in minutes. Chem. Commun. 2007, (21), 2145-2147.

33 Zhao, Y.; Perrier, S., Synthesis of poly(methyl acrylate) grafted onto silica particles by Z-supported RAFT polymerization. Macromol. Symp. 2007, 248, 94-103.

32 Zhao, Y.; Perrier, S., Polymerization via Z-supported raft polymerization. Macromolecules 2006, 39, (25), 8603-8608.

31 Wood, M. R.; Duncalf, D. J.; Rannard, S. P.; Perrier, S., Selective one-pot synthesis of trithiocarbonates, xanthates, and dithiocarbamates for use in RAFT/MADIX living radical polymerizations. Org. Lett. 2006, 8(4), 553-556.

30 Whittaker, M. R.; Goh, Y.-K.; Gemici, H.; Legge, T. M.; Perrier, S.; Monteiro, M. J., Synthesis of monocyclic and linear polystyrene using the reversible coupling/cleavage of thiol/disulfide groups. Macromolecules 2006, 39, (26), 9028-9034.

29 Tang, T.; Castelletto, V.; Parras, P.; Hamley, I. W.; King, S. M.; Roy, D.; Perrier, S.; Hoogenboom, R.; Schubert, U. S., Thermo-responsive poly(methyl methacrylate)-block-poly(N-isopropylacrylamide) block copolymers synthesized by RAFT polymerization: micellization and gelation. Macromol. Chem. Phys. 2006, 207, (19), 1718-1726.

28 Naftaly, M.; Dimitrakopoulos, D.; Miles, R. E.; Brown, S.; Perrier, S. Polymerisation-related changes in THz transmission in SU8 and polystyrene, Conference Digest of the 2006 Joint 31st International Conference on Infrared and Millimeter Waves and 14th International Conference on Terahertz Electronics (Eds.: Shen, X.C.; Lu, W.; Zhang, J.; Dou, W.B.) 2006, 56.

27 Roy, D.; Guthrie, J. T.; Perrier, S., RAFT graft polymerization of 2-(dimethylaminoethyl) methacrylate onto cellulose fibre. Aust. J. Chem. 2006, 59, (10), 737-741.

26 Legge, T. M.; Slark, A. T.; Perrier, S., Thermal stability of reversible addition-fragmentation chain transfer/macromolecular architecture design by interchange of xanthates chain-transfer agents. J. Polym. Sci., Part A: Polym. Chem. 2006, 44, (24), 6980-6987.

25 Takolpuckdee, P.; Mars, C. A.; Perrier, S.; Archibald, S. J., Novel amide-based chain transfer agent for reversible addition fragmentation chain transfer polymerization. Macromolecules 2005, 38, (4), 1057-1060.

24 Takolpuckdee, P.; Mars, C. A.; Perrier, S., Merrifield resin-supported chain transfer agents, precursors for raft polymerization. Org. Lett. 2005, 7, (16), 3449-3452.

23 Roy, D.; Guthrie, J. T.; Perrier, S., Graft polymerization: grafting poly(styrene) from cellulose via reversible addition-fragmentation chain transfer (RAFT) polymerization. Macromolecules 2005, 38, (25), 10363-10372.

22 Perrier, S.; Takolpuckdee, P.; Mars, C. A., Reversible addition-fragmentation chain transfer polymerization mediated by a solid supported chain transfer agent. Macromolecules 2005, 38, (16), 6770-6774.

21 Perrier, S.; Takolpuckdee, P.; Mars, C. A., Reversible addition-fragmentation chain transfer polymerization: end group modification for functionalized polymers and chain transfer agent recovery. Macromolecules 2005, 38, (38), 2033-2036.

20 Perrier, S.; Takolpuckdee, P., Macromolecular design via reversible addition-fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, (22), 5347-5393. Cover Article. 4th Most cited article in the area of Material Science from 2005 to 2011 (Source: Sci Finder Scholar, July 2011) ; Top 10 most accessed articles of JPSA since 2005 and Top 20 most highly cited and widely read articles published in the entire history of the journal (Source: JPSA, January 2010).


19 Liu, B.; Perrier, S., Thermoresponsive micelles from well-defined block copolymers synthesized via reversible addition-fragmentation chain transfer polymerization. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, (16), 3643-3654.

18 Liu, B.; Kazlauciunas, A.; Guthrie, J. T.; Perrier, S., Influence of reaction parameters on the synthesis of hyperbranched polymers via reversible addition fragmentation chain transfer (RAFT) polymerization. Polymer 2005, 46, (17), 6293-6299.

17 Liu, B.; Kazlauciunas, A.; Guthrie, J. T.; Perrier, S., One-pot hyperbranched polymer synthesis mediated by reversible addition fragmentation chain transfer (RAFT) polymerization. Macromolecules 2005, 38, (6), 2131-2136.

16 Perrier, S.; Takolpuckdee, P.; Westwood, J.; Lewis, D. M., Versatile chain transfer agents for reversible addition fragmentation chain transfer (RAFT) polymerization to synthesize functional polymeric architectures. Macromolecules 2004, 37, 2709-2717.

15 Perrier, S.; Haddleton, D. M., Initiating efficiency of poly(ethylene glycol)-based initiators for transition metal mediated living radical polymerization. Eur. Polym. J. 2004, 40, (10), 2277-2286.

14 Perrier, S.; Gemici, H.; Li, S., Poly(ethylene glycol) as solvent for transition metal mediated living radical polymerisation. Chem. Commun. 2004, (5), 604-605.

13 Perrier, S., Developments in polymer architecture and design applicable to surface coatings. Surface Coatings International, Part B: Coatings Transactions 2004, 87, (B4), 235-239.

12 Takolpuckdee, P.; Westwood, J.; Lewis, D. M.; Perrier, S., Polymer architectures via reversible addition fragmentation chain transfer (RAFT) polymerization. Macromol. Symp. 2004, 216, 23-35.

11 Perrier, S.; Jackson, S.G.; Haddleton, D.M.; Ameduri, B.; Boutevin, B. Preparation of fluorinated copolymers by copper-mediated living radical polymerization. Macromolecules 2003, 36(24), 9042-9049.

10 Perrier, S.; Davis, T.P.; Carmichael, A.J.; Haddleton, D.M. Reversible addition-fragmentation chain transfer polymerization of methacrylate, acrylate and styrene monomers in 1-alkyl-3-methylimidazolium hexafluorophosphate. Eur. Polym. J. 2003, 39(3), 417-422.

9 Perrier, S.; Barner-Kowollik, C.; Quinn, J.F.; Vana, P.; Davis, T.P. Origin of inhibition effects in the reversible addition fragmentation chain transfer (RAFT) polymerization of methyl acrylate. Macromolecules 2002, 35(22), 8300-8306

8 Perrier, S.; Davis, T.P.; Carmichael, A.J.; Haddleton, D.M. First report of reversible addition-fragmentation chain transfer (RAFT) polymerization in room temperature ionic liquids. Chem. Commun. 2002, (19), 2226-2227.

7 Perrier, S.; Jackson, S.G.; Haddleton, D.M.; Ameduri, B.; Boutevin, B. Preparation of fluorinated methacrylic copolymers by copper mediated living radical polymerization. Tetrahedron 2002, 58(20), 4053-4059.

6 Perrier, S.; Berthier, D.; Willoughby, I.; Batt-Coutrot, D.; Haddleton, D.M. Living radical polymerization of styrene mediated by copper(I)/N-n-alkyl-2-pyridylmethanimine catalysts. Macromolecules 2002, 35(8), 2941-2948.

5 Perrier, Sebastien; Armes, Steven P.; Wang, X. S.; Malet, F.; Haddleton, David M. Copper(I)-mediated radical polymerization of methacrylates in aqueous solution. J. Polym. Sci., Part A: Polym. Chem. 2001, 39(10), 1696-1707.

4 Wang, X. S.; Malet, F. L. G.; Armes, S. P.; Haddleton, D. M.; Perrier, S. Unexpected viability of pyridyl methanimine-based ligands for transition-metal-mediated living radical polymerization in aqueous media at ambient temperature. Macromolecules 2001, 34(2), 162-164.

3 Haddleton, D.M.; Perrier, S.; Bon, S.A. F. Copper(I)-Mediated Living Radical Polymerization in the Presence of Oxyethylene Groups: Online 1H NMR Spectroscopy To Investigate Solvent Effects. Macromolecules 2000, 33(22), 8246-8251.

2 Perrier S., Haddleton D.M. Effect of water on copper mediated living radical polymerization, Macromol. Symp. 2000, 182, 271-272.

1 Haddleton, D.M.; Heming, A.M.; Jarvis, A.P.; Khan, A.; Marsh, A.; Perrier, S.; Bon, S.A.F.; Jackson, S.G.; Edmonds, R.; Kelly, E.; Kukuli, D.; Waterson, C. Novel polymers from atom transfer polymerization mediated by copper(I) Schiff base complexes. Macromol. Symp. 2000, 7, 201-208.