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Explained: The lifetime of an evaporating liquid drop

The lifespan of a liquid droplet which is transforming into vapour can now be predicted thanks to a theory developed at the University of Warwick. The new understanding can now be exploited in a myriad of natural and industrial settings where the lifetime of liquid drops governs a process’ behaviour and efficiency.

Spiders web with droplets on

Water evaporating into vapour forms part of our daily existence, creating plumes emanating from a boiling kettle and bulging clouds as part of the earth’s water cycle. Evaporating liquid drops are also commonly observed, e.g. as the morning dew disappears off a spider’s web, and are critical for technologies such as fuel-injection combustion engines and cutting-edge evaporative cooling devices for next generation electronics.

Researchers from the School of Engineering and the Mathematics Institute have had the paper ‘Lifetime of a Nanodroplet: Kinetic Effects & Regime Transitions’; published in the journal Physical Review Letters, in which they explore the lifespan of a liquid droplet.

Current theories state that the droplet’s diameter-squared decreases in proportion to time (classical law); however, this period only accounts for a small portion of the drop’s evolution. As the diameter approaches the unobservable micro- and nano-scale, molecular dynamics have to be used as virtual experiments and these show a crossover to a new behaviour, with the diameter now reducing in proportion to time (nano-scale law).

Research at Warwick has shown that this behaviour occurs due to complex physics in the vapour flow, which can result in jumps in temperature across just a few molecules as large as 40 degrees! This behaviour is counter-intuitive to our daily experiences (on the macroscale), where we are used to temperatures changing relatively gradually, but must be accounted for to accurately predict the final stages of an evaporating drop’s life.

Prof. Duncan Lockerby from the School of Engineering comments:

“The main achievement here is the theory’s ability to quickly predict the drop’s lifetime and create a modelling framework that maintains accuracy from typical engineering scales down to cutting-edge nanoscale applications”

Diagram demonstrating the lifetime of a water droplet evapourating

For complete press release, visit this link:

  • Liquids evaporating into vapour is a daily occurrence, and yet the time it takes a liquid droplet to completely evaporate has remained a mystery
  • Researchers at the University of Warwick have analysed this process down to the nano-scale to reveal fascinating new physics in the vapour’s flow
  • The new theory, which accurately predicts the lifetime of droplets can now be exploited for engineering design