Tiny materials one hundred thousand times smaller than the width of a strand of hair could be used to improve solar cell technology. 

A study published this month in Advanced Materials shows that materials as small as 1.2 nanometres across could function in solar cells, which harvest energy from the sun. The inorganic halide materials are templated within carbon nanotubes, tiny tubules formed from carbon atoms.  

The discovery of such small nanowires could potentially lead to new properties and applications of this type of sustainable energy. 

Researchers from the University of Warwick, Oxford Materials and SuperSTEM, a UK national centre for electron microscopy, revealed the absolute minimum limit at which halide perovskite-like structures can be produced as free-standing materials inside carbon nanotube. Halide perovskites have similar structures to calcium titanate and are commonly used in solar panels and light emitting diodes (LEDs). 

Dr Jeremy Sloan, from Warwick’s Department of Physics said: “In contrast to large ‘bulk’ halide perovskites, we show that much smaller ‘picoscale’ halide perovskite structures just a single unit cell or even just one quarter of a unit cell in cross section can be encapsulated in carbon nanotubes ranging between 1.2-1.6nm in diameter.

“Our study shows remarkably similar results to a publication in Journal of the American Chemical Society (JACS) by researchers at the University of Berkeley, further highlighting the potential applications of these tiny materials in solar cells.

“The wider implications of these studies will help to extend the remarkable optoelectronic characteristics of halide perovskites to sub-nanometer, or even picoscale dimensions.”

This work, funded by the Engineering and Physical Sciences Research Council (EPSRC), contributes to the extensive ongoing halide perovskite research carried out at the University’s Physics and Chemistry departments.

Read full paper here in Advanced Materials here: https://doi.org/10.1002/adma.202208575 

See also the related JACS publication here:  

https://doi.org/10.1021/jacs.2c13711 

More about the department here: https://warwick.ac.uk/fac/sci/physics/

Notes to Editors

New Paper published by Reza Kashtiban and Jeremy Sloan in Advanced Materials together with Richard Walton in Warwick Chemistry, Christopher Patrick (formerly Warwick Physics) from Oxford Materials and Quentin Ramasse at FTSC SuperSTEM demonstrate the absolute minimum size limit at which halide perovskites can be formed in Picoperovskites: The Smallest Conceivable Isolated Halide Perovskite Structures Formed within Carbon Nanotubes.

28 March 2023