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Michael Staniforth (PDRA)


Project Details

Historically, Mick worked with the gas phase projects of the Stavros group, exploring the photoexcited dynamics of biologically relevant cromphores such as phenol and pyrrole derivatives using photoion/photoelectron velocity map imaging (VMI). Working from a 'bottom-up'approach, by studying molecules of ever growing complexity up to full biological molecules, the fundemental biophysical processes that govern the photostability of hese complicated biomolecules (such as whole DNA or biological/synthetic sunscreens) can be understood.

Mick is currently working on the design and construction of an exciting new laser lab in collaboration with the physics department which will propel his scientific focus from the gas to the condensed phase. This lab will include beam-lines for transient electronic absoprtion spectroscopy (UV/white light), transient vibrational absorption spectroscop (UV/IR), time resolved opitcal/terahertz spectrscopy and time resolved terahertz/terahertz spectroscopy. This wide range of experimental techniques will allow Mick and the Stavros and Lloyd-Hughes groups to propel their research into a vast array of new areas such as biophysics, catalysis and materials science. Alongside this experimental work, Mick also augments results with high level theoretical calculations.




A generic π* shape resonance observed in energy-dependent photoelectron angular distributions from two-colour, resonant multiphoton ionization of difluorobenzene isomers

M. Staniforth, S. Daly, K. L. Reid and I. Powis, J. Chem. Phys. 139 (2013) 064304

Rotationally Resolved Photoelectron Angular Distributions from a Nonlinear Polyatomic Molecule

P. Hockett, M. Staniforth, K. L. Reid and D. Townsend, Phys. Rev. Lett. 102 (2009) 253002

Photoelectron angular distributions from rotationally state-selected NH3(B1E′′): dependence on ion rotational state and polarization geometry

P. Hockett, M. Staniforth and K. L. Reid, Mol. Phys. 108 (2010) 1045

Photoionization Dynamics of Ammonia (B1E′′): Dependence on Ionizing Photon Energy and Initial Vibrational Level

P. Hockett, M. Staniforth and K. L. Reid, J. Phys. Chem. A 114 (2010) 11330


Recent advances in experimental techniques to probe fast excited-state dynamics in biological molecules in the gas phase: dynamics in nucleotides, amino acids and beyond

M. Staniforth and V.G. Stavros, Proc. R. Soc. A, 469 (2013) 20130458

Excited state dynamics in resorcinol: Internal conversion vs. quantum tunnelling

J. D. Young, M. Staniforth, A. S. Chatterley, M.J. Paterson, G. M. Roberts, and V. G. Stavros Phys. Chem. Chem. Phys., 16 (2014) 550

Relaxation dynamics of photoexcited dihydroxybenzene: A comparative study

M. Staniforth, A.S. Chatterley, J.D. Young, G.M. Roberts and V.G. Stavros, Biomedical Spectroscopy and Imaging, 3 (2014) 271

Towards understanding photodegradation pathways in lignins: The role of intramolecular hydrogen bonding in excited states

J.D. Young, M. Staniforth, J.C. Dean, G.M. Roberts, F. Mazzoni, T.N.V. Karsili, M.N.R. Ashfold, T.S. Zwier and V.G. Stavros, J. Phys. Chem. Lett., 5 (2014) 2138

Ultrafast excited state dynamics in 2,4-dimethylpyrrole

M. Staniforth, J.D. Young, D.R. Cole, T.N.V. Karsili, M.N.R. Ashfold and V.G. Stavros, J. Phys. Chem. A., 118 (2014) 10909

Bridging the Gap between the Gas and Solution Phase: Solvent Specific Photochemistry in 4-tert-Butylcatechol

Michael D. Horbury, Lewis A. Baker, Wen-Dong Quan, Jamie D. Young, Michael Staniforth, Simon E. Greenough, and Vasilios G. Stavros, J. Phys. Chem. A. 119 (2015) 11989

Torsional motion of the chromophore catechol following the absorption of ultraviolet light

J. D. Young, M. Staniforth, M. J. Paterson, and V. G. Stavros, Phys. Rev. Lett., 114 (2015) 233001

Probing Rotational Motion in 4-tert-Butylcatechol through H Atom Photofragmentation: Deviations from Axial Recoil

M. Staniforth, J. D. Young, and V. G. Stavros, J. Phys. Chem. A, 119 (2015) 12131

Extreme Population Inversion in the Fragments Formed by UV Photoinduced SH Bond Fission in 2-Thiophenethiol.

R.A. Ingle, T.N.V. Karsili, G. Dennis, M. Staniforth, V.G. Stavros and M.N.R. Ashfold, Phys. Chem. Chem. Phys., 18 (2016) 11401

Towards Elucidating the Photochemistry of the Sunscreen Filter Ethyl Ferulate Using Time-Resolved Gas-Phase Spectroscopy

N.D.N. Rodrigues, M. Staniforth, J.D. Young, J.R. Gord, P.S. Walsh, T.S. Zwier, V.G. Stavros, Farad. Discuss. (2016)

Bottom-up excited state dynamics of two cinnamate-based sunscreen filter molecules

Y. Peperstraete, M. Staniforth, L.A. Baker, N.D.N. Rodrigues, N.C. Cole-Filipiak, W.D. Quan, and V.G. Stavros

Photophysics of sunscreen molecules in the gas-phase: a stepwise approach towards understanding and developing next generation sunscreens

N.D.N. Rodrigues, M.Staniforth and V.G. Stavros

Ultrafast dissociation dynamics of 2-Ethylpyrrole

N.C. Cole-Filipiak, M. Staniforth, N.D.N. Rodrigues, Y. Peperstraete, and V.G Stavros

First Step toward a Universal Fluorescent Probe: Unravelling the Photodynamics of an Amino–Maleimide Fluorophore

M. Staniforth, W.D. Quan, T.N.V. Karsili, L.A. Baker, R.K. O’Reilly, and V.G. Stavros

Photophysics of the sunscreen ingredient menthyl anthranilate and its precursor methyl anthranilate: A bottom-up approach to photoprotection

N.D.N Rodrigues, N.C. Cole-Filipiak, M.D. Horbury, M. Staniforth, T.N.V. Karsili, Y. Peperstraete, and V.G. Stavros


In Preparation