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Next-generation metal–air and flow batteries using MOF-derived porous electrocatalysts

A research project focused on developing advanced porous materials for sustainable, high-energy-density batteries. The project will investigate how metal–organic frameworks (MOFs) can be transformed into efficient bifunctional electrocatalysts for both oxygen reduction and evolution reactions, advancing the performance of next-generation metal–air and redox-flow batteries.

Primary supervisor: Dr Volkan Degirmenci - Email: V.Degirmenci@warwick.ac.uk

Metal–air batteries such as zinc–air and lithium–air systems are among the most promising candidates for grid and portable energy storage due to their high theoretical energy density and use of abundant materials. However, their commercial adoption is limited by the sluggish oxygen reactions that occur at the air electrode.

This project will develop novel porous carbons and hybrid metal–nitrogen–carbon catalysts derived from bimetallic MOFs (e.g. Co–Zn, Fe–Ni). Through controlled synthesis, doping, and thermal transformation, the student will create high-surface-area conductive materials with atomically dispersed active sites. These catalysts will be characterised using electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy, and tested electrochemically for oxygen reduction and evolution. The most promising materials will be integrated into prototype zinc–air or flow-battery cells to evaluate efficiency and cycling stability.

The project can be directed toward materials synthesis, advanced characterisation, or electrochemical testing, depending on the student’s background and interests.


The University of Warwick provides an inclusive working and learning environment, recognising and respecting every individual’s differences. We welcome applications from individuals who identify with any of the protected characteristics defined by the Equality Act 2010.

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