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3.2 mm HXY H13888

Probe description: PH MASDVT 850W6 BL3.2 X/Y/H

Operating instructions

Additional components: Serial C: 22pF; Range Coil: 10 turns HZ09009

Inserts available

x/y combination X f/MHz Y f/MHz Modification mode Description
insert
Part no:
29Si/15N-2H 168.9 86-130.5 Serial-C in; λ/4 5 turns
12pF
HZ16569
13C/15N-2H 213.7 86 - 130.5 Serial-C in; λ/4

4 turns
8.2pF

HZ16499
13C/14N 213.7 61.4 range coil in; Serial C out; λ/4 at 14N position

4 turns
8.2pF

HZ16499
23Na/15N-2H 224.8 86 -130.5 Serial-C in; λ/4 5 turns
6.8pF
HZ16570
23Na/29Si 224.8 168.9 Serial-C in; λ/2 5 turns
6.8pF
HZ16570
23Na/14N 224.8 61.4 range coil in; Serial C out; λ/4 at 14N position 5 turns
6.8pF
HZ16570
27Al/14N-29Si 221.5 61.4-168.9 the same modifications as 23Na 5 turns
6.8pF
HZ16571
11B/17O-29Si 272.7 115.2-168.9 Serial-C in; λ/2 6 turns
3.3pF
HZ16568

 

Probe Test Results (Stated 90o pulse lengths are the best achieved during installation. To reduce risk of damage to the probes, facility users should use slightly lower RF nutation frequencies (i.e. longer 90o pulse lengths) were possible. Please discuss with the facility manager appropriate RF nutation frequencies for your experiments.)

Insert 29Si/15N-2H

Nuc 90o pulse

Pulse power
level (db)

Pulse
power (W)
Configuration
29Si/15N-2H
Sample Remarks
29Si 3.25 -3 536 λ/4 + serial C Si-Grease  
15N 5.3 -2 556 λ/4 + serial C Glycine (CP)  
1H 2.23 0 178 λ/4 + serial C Glycine

 

Insert 13C/15N-2H :

Nuc 90o pulse

Pulse power
level (db)

Pulse
power (W)
Configuration
13C/15N-2H
Sample Remarks
79Br 3.5 -1 368 λ/4 + serial C KBr  
13C 3.1 -0.6 350 λ/4 + serial C Adamantane line width 1.8Hz
1H 2 -1.3 241 λ/4 + serial C Adamantane there is a 1H background visible
13C 2.5 -.9 375 λ/4 + serial C Glycine (CP) S/N 79
1H 1.95 -0.3 191 λ/4 + serial C Glycine 100kHz for 50ms decoupling
15N 5.2/4.1 -0.77/-3 420/700 λ/4 + serial C Glycine (CP/CP90) (enriched)  
14N 5.5 -3 795 λ/4 at 14N +range coil NH4Cl  
14N 5 -4 1001 λ/4 at 14N +range coil NH4Cl  
1H 1.8 -1.3 241 λ/4 at 14N +range coil Adamantane  
13C 3.4 -2.2 506 λ/4 at 14N +range coil Adamantane  

 

Insert 13C/15N-2H:

Nuc 90o pulse

Pulse power
level (db)

Pulse
power (W)
Configuration
13C/15N-2H
Sample Remarks
29Si 6.5 -1 620 λ/2+ serial C Si-Grease  
13C 2.6 -0.9 375 λ/2 + serial C Glycine (CP) S/N 82
1H 2.1 -0.3 191 λ/2 + serial C Glycine  

 

Insert 23Na/15N-2H

Nuc 90o pulse

Pulse power
level (db)

Pulse
power (W)
Configuration
23Na/15N-2H
Sample Remarks
29Si 5.5 -2.5 477 λ/2 + serial C Si-Grease  
15N 4.8 -2 556 λ/4 + serial C Glycine (CP)  
1H 2.2 0 179 λ/4 + serial C Glycine  
23Na 2.88 -2 464 λ/4 + serial C NaCl  
23Na 2.35 -2 464 λ/2 + serial C NaCl  

 

Insert 27Al/15N-2H

Nuc 90o pulse

Pulse power
level (db)

Pulse
power (W)
Configuration
27Al/15N-2H
Sample Remarks
15N 4.8 -2 556 λ/4 + serial C Glycine (CP)  
1H 2.15 0 178 λ/4 + serial C Glycine

 

Insert 11B/17O-29Si)

Nuc 90o pulse

Pulse power
level (db)

Pulse
power (W)
Configuration
11B/17O-29Si
Sample Remarks
11B 1.55 -2 395 λ/2 + serial C Borax  
29Si 5.1 -3 536 λ/2 + serial C Si-Grease

 

DR mode

Nuc 90o pulse

Pulse power
level (db)

Pulse
power (W)
Configuration
Sample Remarks
13C 2.17 -0.6 350 λ/2 Adamantane  
1H 1.65 -1.3 241 λ/2 Adamantane  
13C 1.7 1 242 λ/2 Glycine (CP) S/N 121
1H 1.95 -0.3 191 λ/4 Glycine  
15N 3.8 -0.77 420 λ/4 1hole down Glycine (CP) S/N 15
1H 2.25 1 142 λ/4 1hole down Glycine  
14N 3.7 -3 715 λ/4 1hole down NH4Cl  

 

Tuning range (measured on the bench, double resonnace mode 1H-X )

λ/2 mode

165→283MHz

Includes 29Si(168.871), 127I(170.064), 207Pb( 177.825), 111Cd(180.332), 165Ho(181.390), 195Pt(182.723), 113In(185.859), 115In(186.257), 113Cd(188.642), 99Tc(191.321), 185Re(191.459), 187Re(193.389), 59Co(201.680), 121Sb(203.410), 69Ga(204.012), 159Tb(204.340), 45Sc(206.480), 93Nb(208.047), 55Mn(210.708), 151Eu(211.310), 79Br(212.959), 13C(213.733), 27Al (221.483), 123Te(222.443), 51V(223.575), 23Na(224.841), 63Cu(225.382), 81Br(229.555), 129Xe(236.387), 65Cu(241.431), 71Ga(259.222), 141Pr(260.270), 125Te(268.173), 11B(272.714), 115Sn(278.109), 87Rb(278.124),

λ/4 mode

100→228 MHz

Inlcudes: 181Ta( 101.912), 123Sb( 110.153), 133Cs(111.487), 138La( 112.152), 17O(115.230), 9Be( 119.440), 139La(120.068), 6 Li(125.087), 2H(130.480), 209Bi(136.589), 75As(145.542), 171Yb(148.744), 199Hg(152.242), 77Se(162.108), 29Si(168.871), 127I(170.064), 207Pb( 177.825), 111Cd( 180.332), 165Ho(181.390), 195Pt(182.723), 113In(185.859), 115In(186.257), 113Cd(188.642), 99Tc(191.321), 185Re(191.459), 187Re(193.389), 59Co(201.680), 121Sb(203.410), 69Ga(204.012), 159Tb(204.340), 45Sc(206.480), 93Nb(208.047), 55Mn(210.708), 151Eu(211.310), 79Br(212.959), 13C(213.733), 27Al (221.483), 123Te(222.443), 51V(223.575), 23Na(224.841), 63Cu(225.382)

 

Temperature calibration for the 3.2 mm HXY probe spinning at 20 kHz.

Bruker indicated
temperature (oC)
Real temperature
calibrated with lead nitrate (oC)
26 51
33 70
50 90
72 111
80 133*
96 152*
116 178*

*Booster connected