Richard was born in the town of Grantham, Lincolnshire and commenced his chemistry studies at Durham University, receiving his Master’s degree in 2014. He completed a final year project under the supervision of Dr. Ezat Khosravi utilizing thiol-ene click chemistry in the synthesis of thermosetting materials for coating applications. Later that year Richard joined the group of Professor David Haddleton to undertake a PhD at the University of Warwick, developing copper mediated polymerization strategies for the controlled polymerization of methacrylic, styrenic and acrylic monomers, with an industrial project synthesising cationic polymers for applications in gene delivery. He has spent 2 months as a visiting scholar at the University of California Santa Barbara under the supervision of Professor Craig Hawker and is currently completing the final year of his PhD.
14. Cu(0)-RDRP of styrene: balancing initiator efficiency and dispersity
Richard Whitfield, Athina Anastasaki, Glen R. Jones, D. M. Haddleton, Polym. Chem. Just accepted
13. Efficient Binding, Protection, and Self-Release of dsRNA in Soil by Linear and Star Cationic Polymers
Richard Whitfield, Athina Anastasaki, Nghia P. Truong, Alexander B. Cook, Marta Omedes-Pujol, Vanessa Loczenski Rose, Tuan A. H. Nguyen, James A. Burns, Sébastien Perrier, Thomas P. Davis, David M. Haddleton, ACS Macro Letters, Just accepted DOI: 10.1021/acsmacrolett.8b00420
12. Cationic and hydrolysable branched polymers by RAFT for complexation and controlled release of dsRNA
Alexander Cook, Raoul Peltier, Matthias Hartlieb, Richard Whitfield, Guillaume Moriceau, James Burns, David Haddleton, Sebastien Perrier, Polymer Chemistry, DOI: 10.1039/C8PY00804C
11. Copper mediated polymerization without external deoxygenation or oxygen scavengers
Evelina Liarou§, Richard Whitfield§, Athina Anastasaki, Nikolaos G Engelis, Glen R Jones, Kelly Velonia, David M Haddleton, Angewandte Chemie, https://doi.org/10.1002/anie.201804205
10. Copper Mediated Reversible Deactivation Radical Polymerization in Aqueous Media
Glen R Jones, Athina Anastasaki, Richard Whitfield, Nikolaos G Engelis, Evelina Liarou, David M Haddleton, Angewandte Chemie, https://doi.org/10.1002/ange.201802091
9. Sequence-Controlled Methacrylic Multiblock Copolymers: Expanding the Scope of Sulfur-Free RAFT
Nikolaos G Engelis, Athina Anastasaki, Richard Whitfield, Glen R Jones, Evelina Liarou, Vasiliki Nikolaou, Gabit Nurumbetov, David M Haddleton Macromolecules, 2018, 51 (2), pp 336–342
8. One-Pot Sequence-Controlled (SC) Multiblock Copolymers via Copper-Mediated Polymerization
Athina Anastasaki, Richard Whitfield, Vasiliki Nikolaou, Nghia P Truong, Glen R Jones, Nikolaos G Engelis, Evelina Liarou, Michael R Whittaker, David M Haddleton, Sequence-Controlled Polymers, John Wiley & Sons, 2018.
7. Cu (0)-RDRP of methacrylates in DMSO: importance of the initiator
Glen R. Jones §, Richard Whitfield §, Athina Anastasaki, Nuttapol Risangud, Alexandre Simula, Daniel J. Keddie, David M. Haddleton, Polym. Chem., 2018,9, 2382-2388
6. Practical Chain-End Reduction of Polymers Obtained with ATRP
Will R. Gutekunst, Athina Anastasaki, David J. Lunn, Nghia P. Truong, Richard Whitfield, Glen R. Jones, Nicolas J. Treat, Allison Abdilla, Bryan E. Barton, Paul G. Clark, David M. Haddleton, Thomas P. Davis, Craig J. Hawker. Macromol. Chem. 2017, 218, 1700107.
5. Specific and Differential Binding of N-Acetylgalactosamine Glycopolymers to the Human Macrophage Galactose Lectin and Asialoglycoprotein Receptor
Joji Tanaka, Anne S. Gleinich, Qiang Zhang, Richard Whitfield, Kristian Kempe, David M. Haddleton, Thomas P. Davis, Sébastien Perrier, Daniel A. Mitchell, Paul Wilson, Biomacromolecules, 2017, 18 (5), pp 1624–1633
4. Universal Conditions for the Controlled Polymerization of Acrylates, Methacrylates and Styrene via Cu (0)-RDRP.
Richard Whitfield, Athina Anastasaki, Vasiliki Nikolaou, Glen R Jones, Nikolaos G Engelis, Emre H Discekici, Carolin Fleischmann, Johannes Willenbacher, Craig J Hawker, David M Haddleton, J. Am. Chem. Soc., 2017, 139 (2), pp 1003–1010
3. Well-defined PDMAEA stars via Cu (0)-mediated reversible deactivation radical polymerization
Richard Whitfield, Athina Anastasaki, Nghia P Truong, Paul Wilson, Kristian Kempe, James A Burns, Thomas P Davis, David M Haddleton, Macromolecules, 2016, 49 (23), pp 8914–8924
2. Aqueous copper (II) photoinduced polymerization of acrylates: Low copper concentration and the importance of sodium halide salts
Glen R Jones, Richard Whitfield, Athina Anastasaki, David M Haddleton, J. Am. Chem. Soc., 2016, 138 (23), pp 7346–7352
1. Discrete copper (II)-formate complexes as catalytic precursors for photo-induced reversible deactivation polymerization
Vasiliki Nikolaou, Athina Anastasaki, Francesca Brandford-Adams, Richard Whitfield, Glen R. Jones, Gabit Nurumbetov, David M. Haddleton, Polym. Chem., 2016, 7, 191-197.
Controlled Living radical Polymerization
Light mediated polymerization
Polymer/RNA complexation and release strategies
European Polymer Federation (EPF), Dresden, Germany, 2015.
Warwick Polymer Conference, 2016
Syngenta Collaborative Conference, Jealotts Hill, 2016
ACS National Meeting (Spring), San Francisco, USA, 2017
Syngenta Collaborative Conference, Jealotts Hill, 2017
IUPAC World Polymer Congress (Macro18), Cairns, Australia 2018
American Chemical Society (ACS)
Royal Society of Chemistry (RSC)
Macro group UK.
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