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4 mm X/Y/H-F H13694

Probe description: PH MASDVT 850W6 BL4 X/Y/H-F

Operating instructions

Additional components: Serial C: 2.7pF serial C 6.8pF; Range Coil: 5.5 turns HZ12211; range coil 2.5 turns HZ12212; range coil 8 turns HZ09351

Inserts available

VT calibration report Temperature calibration temperature- spinning calibration

x/y combination X f/MHz Y f/MHz Modification mode Description
insert
Part no:
(1H) 31P/17O 344 115.2 λ/4; range coil 2.5 turns 4 turns+1turn
4.7pF+3.3pF
HZ16627
(19F) 31P/17O 344 115.2 λ/2; range coil 2.5 turns 4 turns+1turn
4.7pF+3.3pF
HZ16627
31P/29Si-23Na 344 168.9 - 224.8 Serial-C 6.8pF in; range coil 5.5 turns; λ/2

4 turns
3.3pF

HZ16619
31P/13C-11B 344 213.7 - 272.7 Serial-C 2.7pF in; range coil 5.5 turns; λ/2

2 turns
10pF

HZ15223
31P/(13C-11B) 27Al 344 169.8 - 266.8 Serial-C 6.8pF; range coil 5.5 turns; λ/2

2 turns
10pF

HZ15223
11B/17O-29Si 272.7 115.2-168.9 λ/2; range coil 8 turns 5 turns
3.9pF
HZ16568
11B/29Si-23Na 272.7 115.2-168.9 Serial-C 6.8pF in; λ/2 2 turns+1turn
12pF+3.3pF
HZ16620
7Li/6Li 330.4 123.0 - 210.5 range coil 4.5 turns; λ/2

5 turns
3.3pF

H126631

 

Frequency table (measured on the bench) in double resonance mode

X-nuclei X-range
MHz
Modification mode
14N-29Si

53.3-202.7
only 1H possible

No serial C, λ/4, 19F not possible
29Si-71Ga (for 1H) 142.5-265.7 No serial C, λ/2
6Li-23Na (for 19F) 121.3-243.8 No serial C, λ/2
13C-23Na (for 1H) 203-324.8 2.7pF serial C, λ/4, 19F not possible
27Al-31P (for 1H) 219.0-347.8 2.7pF serial C, λ/2
27Al-11B (for 19F) 214.6-340.6 2.7pF serial C, λ/2
29Si-71Ga (for 1H) 152.5-271.5 6.8pF serial C, λ/4
29Si-71Ga (for 19F) 151.5-267.2 6.8pF serial C, λ/4
13C-11B (for 1H) 187.5-321.3 6.8pF serial C, λ/2
13C-11B (for 19F) 179.5-300.4 6.8pF serial C, λ/2

 

Probe Test Results (Stated 90o pulse lengths are the best achieved during installation. To reduce risk of damage to the probes, facility users should use slightly lower RF nutation frequencies (i.e. longer 90o pulse lengths) were possible. Please discuss with the facility manager appropriate RF nutation frequencies for your experiments.)

Insert 31P/17O

Nuc 90o pulse Pulse power
level (db)
Pulse
power (W)
Configuration
31P/17O
Sample Remarks
31P 3.67 -3 528 λ/2, range coil 2.5 ADP 19F only
19F 2.12 0 251 λ/2, range coil 2.5 ADP 19F only
1H 3.3 0 142 λ/4, range coil 2.5 ADP 1H only
31P 5.5 -3.2 550 λ/4, range coil 2.5 ADP 1H only
1H 3.75 2 113 λ/4, range coil 2.5 ADP 1H only

 

Insert 31P/29Si-23Na

Nuc 90o pulse Pulse power
level (db)
Pulse
power (W)
Configuration
31P/29Si-23Na
Sample Remarks
13C 3.92 -3.6 679 λ/2, 6.8pF,5.5Wnd Glycine S/N 97
1H 2.95 -1 225 λ/2, 6.8pF,5.5Wnd Glycine  
13C 5.4 -1 373 λ/2, 6.8pF,5.5Wnd Glycine  

 

Insert 31P/13C-11B

Nuc 90o pulse Pulse power
level (db)
Pulse
power (W)
Configuration
31P/13C-11B
Sample Remarks
1H 3.8 -2 283 λ/2, range coil 5.5, 2.7pF ADP  
31P 3.8 -2 419 λ/2, range coil 5.5, 2.7pF ADP  
1H 3.95 -2 283 λ/2, range coil 5.5, 2.7pF Glycine  
13C 5.5 -1 373 λ/2, range coil 5.5, 2.7pF Glycine  
13C 4.2 -3 591 λ/2, range coil 5.5, 2.7pF Glycine  

 

Insert 11B/17O-29Si

Nuc 90o pulse Pulse power
level (db)
Pulse
power (W)
Configuration
11B/17O-29Si
Sample Remarks
11B 2 -3.67 580 λ/2, range coil 8 Borax  

 

 

Insert 11B/29Si-23Na

Nuc 90o pulse Pulse power
level (db)
Pulse
power (W)

Configuration
11B/29Si-23Na

Sample Remarks
11B 1.95 -3.67 580 λ/2, 6.8pF Borax  
11B 30 23 1.25 λ/2, 6.8pF Borax  
27Al 3.83 -4 582 λ/2, 6.8pF Al2NO3 liquid  
27Al 32 14 9 λ/2, 6.8pF Al2NO3 liquid  

 

DR mode

Nuc 90o pulse

Pulse power
level (db)

Pulse
power (W)
Configuration
Sample Remarks
79Br 3 -0.3 313 λ/2 KBr  
13C 3 -0.8 366 λ/2 Adamantane line width 2Hz
1H 3 -0.7 210 λ/2 Adamantane there is a 1H background visible
13C 3.45 0 305 λ/2 Glycine (CP) S/N 212
1H 2.75 -0.7 210 λ/2 Glycine  

29Si

3.5 0 268 λ/2 Q8M8  
1H 3.65 1.4 113 λ/2 Q8M8  
19F 1.85 -0.7 295 λ/2 PVDF  
15N 5.8 -1 440 λ/4 one down Glycine (CP) S/N 23
1H 3.5 1 142 λ/4 one down Glycine  
31P 3.1 3 132 λ/2, 2.7pF ADP S/N 4137
1H 3.5 1 142 λ/2, 2.7pF ADP  
19F 2.05 -0.7 295 λ/2 PVDF  
13C 3.4 0 305 λ/2 PVDF (19F-13C cp)  
13C 3.0 -1.4 421 λ/2 PVDF (19F-13C cp90)