4 mm X/Y/H-F H13694

Probe description: PH MASDVT 850W6 BL4 X/Y/H-F

Additional components: Serial C: 2.7pF serial C 6.8pF; Range Coil: 5.5 turns HZ12211; range coil 2.5 turns HZ12212; range coil 8 turns HZ09351

Inserts available

VT calibration report Temperature calibration temperature- spinning calibration

x/y combination	X f/MHz	Y f/MHz	Modification mode	Description insert	Part no:
(¹H) ³¹P/¹⁷O	344	115.2	λ/4; range coil 2.5 turns	4 turns+1turn 4.7pF+3.3pF	HZ16627
(¹⁹F) ³¹P/¹⁷O	344	115.2	λ/2; range coil 2.5 turns	4 turns+1turn 4.7pF+3.3pF	HZ16627
³¹P/²⁹Si-²³Na	344	168.9 - 224.8	Serial-C 6.8pF in; range coil 5.5 turns; λ/2	4 turns 3.3pF	HZ16619
³¹P/¹³C-¹¹B	344	213.7 - 272.7	Serial-C 2.7pF in; range coil 5.5 turns; λ/2	2 turns 10pF	HZ15223
³¹P/_{(¹³C-¹¹B)} ²⁷Al	344	169.8 - 266.8	Serial-C 6.8pF; range coil 5.5 turns; λ/2	2 turns 10pF	HZ15223
¹¹B/¹⁷O-²⁹Si	272.7	115.2-168.9	λ/2; range coil 8 turns	5 turns 3.9pF	HZ16568
¹¹B/²⁹Si-²³Na	272.7	168.8-224.8	Serial-C 6.8pF in; λ/2	2 turns+1turn 12pF+3.3pF	HZ16620
⁷Li/⁶Li	330.4	123.0 - 210.5	range coil 4.5 turns; λ/2	5 turns 3.3pF	H126631

Frequency table (measured on the bench) in double resonance mode

X-nuclei	X-range MHz	Modification mode
¹⁴N-²⁹Si	53.3-202.7 only ¹H possible	No serial C, λ/4, ¹⁹F not possible
²⁹Si-⁷¹Ga	(for ¹H) 142.5-265.7	No serial C, λ/2
⁶Li-²³Na	(for ¹⁹F) 121.3-243.8	No serial C, λ/2
¹³C-²³Na	(for ¹H) 203-324.8	2.7pF serial C, λ/4, ¹⁹F not possible
²⁷Al-³¹P	(for ¹H) 219.0-347.8	2.7pF serial C, λ/2
²⁷Al-¹¹B	(for ¹⁹F) 214.6-340.6	2.7pF serial C, λ/2
²⁹Si-⁷¹Ga	(for ¹H) 152.5-271.5	6.8pF serial C, λ/4
²⁹Si-⁷¹Ga	(for ¹⁹F) 151.5-267.2	6.8pF serial C, λ/4
¹³C-¹¹B	(for ¹H) 187.5-321.3	6.8pF serial C, λ/2
¹³C-¹¹B	(for ¹⁹F) 179.5-300.4	6.8pF serial C, λ/2

Probe Test Results (Stated 90^o pulse lengths are the best achieved during installation. To reduce risk of damage to the probes, facility users should use slightly lower RF nutation frequencies (i.e. longer 90^o pulse lengths) were possible. Please discuss with the facility manager appropriate RF nutation frequencies for your experiments.)

Insert ³¹P/¹⁷O

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ³¹P/¹⁷O	Sample	Remarks
³¹P	3.67	-3	528	λ/2, range coil 2.5	ADP	¹⁹F only
¹⁹F	2.12	0	251	λ/2, range coil 2.5	ADP	¹⁹F only
¹H	3.3	0	142	λ/4, range coil 2.5	ADP	¹H only
³¹P	5.5	-3.2	550	λ/4, range coil 2.5	ADP	¹H only
¹H	3.75	2	113	λ/4, range coil 2.5	ADP	¹H only

Insert ^31P/²⁹Si-²³Na

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ^31P/²⁹Si-²³Na	Sample	Remarks
¹³C	3.92	-3.6	679	λ/2, 6.8pF,5.5Wnd	Glycine	S/N 97
¹H	2.95	-1	225	λ/2, 6.8pF,5.5Wnd	Glycine
¹³C	5.4	-1	373	λ/2, 6.8pF,5.5Wnd	Glycine

Insert ³¹P/¹³C-¹¹B

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ³¹P/¹³C-¹¹B	Sample	Remarks
¹H	3.8	-2	283	λ/2, range coil 5.5, 2.7pF	ADP
³¹P	3.8	-2	419	λ/2, range coil 5.5, 2.7pF	ADP
¹H	3.95	-2	283	λ/2, range coil 5.5, 2.7pF	Glycine
¹³C	5.5	-1	373	λ/2, range coil 5.5, 2.7pF	Glycine
¹³C	4.2	-3	591	λ/2, range coil 5.5, 2.7pF	Glycine

Insert ¹¹B/¹⁷O-²⁹Si

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ¹¹B/¹⁷O-²⁹Si	Sample	Remarks
¹¹B	2	-3.67	580	λ/2, range coil 8	Borax

Insert ¹¹B/²⁹Si-²³Na

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration ¹¹B/²⁹Si-²³Na	Sample	Remarks
¹¹B	1.95	-3.67	580	λ/2, 6.8pF	Borax
¹¹B	30	23	1.25	λ/2, 6.8pF	Borax
²⁷Al	3.83	-4	582	λ/2, 6.8pF	Al₂NO₃ liquid
²⁷Al	32	14	9	λ/2, 6.8pF	Al₂NO₃ liquid

DR mode

Nuc	90^o pulse	Pulse power level (db)	Pulse power (W)	Configuration	Sample	Remarks
⁷⁹Br	3	-0.3	313	λ/2	KBr
¹³C	3	-0.8	366	λ/2	Adamantane	line width 2Hz
¹H	3	-0.7	210	λ/2	Adamantane	there is a ¹H background visible
¹³C	3.45	0	305	λ/2	Glycine (CP)	S/N 212
¹H	2.75	-0.7	210	λ/2	Glycine
²⁹Si	3.5	0	268	λ/2	Q8M8
¹H	3.65	1.4	113	λ/2	Q8M8
¹⁹F	1.85	-0.7	295	λ/2	PVDF
¹⁵N	5.8	-1	440	λ/4 one down	Glycine (CP)	S/N 23
¹H	3.5	1	142	λ/4 one down	Glycine
³¹P	3.1	3	132	λ/2, 2.7pF	ADP	S/N 4137
¹H	3.5	1	142	λ/2, 2.7pF	ADP
¹⁹F	2.05	-0.7	295	λ/2	PVDF
¹³C	3.4	0	305	λ/2	PVDF (19F-13C cp)
¹³C	3.0	-1.4	421	λ/2	PVDF (19F-13C cp90)