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1.3 mm probe X/Y/H-F H13863

Probe description: PH MASDVT 850W6 BL1.3 X/Y/H-F

Operating instructions

Maximum spinning speed 65kHz

Additional components: shunt capacitor 220pF; shunt capacitor 180pF

Inserts available:

x/y combination X f/MHz Y f/MHz Modification mode Description
insert
Part no:
29Si/15N-2H 168.9 86-130.5 λ/4 5 turns+ 1turn
12pF+3.3pF
HZ16604
13C/15N-2H 213.7 86 - 130.5 λ/4

4 turns+1 turn
8.2pF+3.3pF

HZ15355
23Na/15N-2H 224.8 86 -130.5 λ/4 5 turns+ 1turn
6.8pF+3.3pF
HZ16606
23Na/29Si 224.8 168.9 λ/2 5 turns+ 1turn
6.8pF+3.3pF
HZ16606
23Na/14N 224.8 61.4 with 220pF shunt and λ/4 5 turns+ 1turn
6.8pF+3.3pF
HZ16606
27Al/14N-29Si 221.5 61.4-168.9 the same modifications as 23Na
with 180pF for 14N
5 turns+ 1turn
6.8pF+3.3pF
HZ16605
11B/17O-29Si 272.7 115.2-168.9 λ/2 6 turns+ 1turn
3.3pF+3.3pF
HZ16607

 

Probe Test Results (Stated 90o pulse lengths are the best achieved during installation. To reduce risk of damage to the probes, facility users should use slightly lower RF nutation frequencies (i.e. longer 90o pulse lengths) were possible. Please discuss with the facility manager appropriate RF nutation frequencies for your experiments.)

insert 29Si/15N-2H:

Nuc 90opulse

Pulse power
level (db)

Pulse
power (W)
Configuration
29Si/15N-2H
Sample Remarks
29Si 1.7 1 213 λ/4 Si-grease  
15N 2 -1 442 λ/4 Glycine (CP) S/N=5 (for 16 scans)
1H 1.23 4 71 λ/4 Glycine acquisition time tested 45ms

 

insert 13C/15N-2H:

Nuc 90opulse

Pulse power
level (db)

Pulse
power (W)
Configuration
13C/15N-2H
Sample Remarks
79Br 1.5 3.3 136 λ/4 KBr  
13C 1.5 3.3 142 λ/4 Adamantane line width 1.6Hz
1H 1 1.6 123 λ/4 Adamantane there is a 1H background visible
13C 2 5 96 λ/4 Glycine (CP) S/N 42 (for 16 scans)
1H 1.23 3.6 78 λ/4 Glycine 100kHz for 50ms decoupling
15N 3.45 -2 556 λ/4 Glycine (CP) (enriched)  
19F 0.8 0 187 λ/4 for 19F pvdf  
19F 1.15 7 50 λ/4 for 19F pvdf there is a 19F background visible
13C 1.8 4 121 λ/4 for 19F pvdf (19F CP)  

 

insert 23Na/15N-29Si:

Nuc 90opulse

Pulse power
level (db)

Pulse
power (W)
Configuration
23Na/15N-29Si
Sample Remarks
23Na 1.43 2 185 λ/4 NaCl  
15N 2 -1 442 λ/4 Glycine (CP)  
1H 1.23 4 71 λ/4 Glycine  
14N 2.3 0 398 λ/4 NH4Cl  

 

insert 27Al/15N-29Si:

Nuc 90opulse

Pulse power
level (db)

Pulse
power (W)
Configuration
27Al/15N-29Si
Sample Remarks
27Al 1.6 2 156 λ/4 Al2NO3  
15N 2 -1 442 λ/4 Glycine (CP)  
1H 1.23 4 71 λ/4 Glycine  

 

insert 11B/29Si-17O:

Nuc 90opulse

Pulse power
level (db)

Pulse
power (W)
Configuration
11B/29Si-17O
Sample Remarks
11B 1.15 3.3 116 λ/2 Borax  
2H 2.3 0 232 λ/2 D2O  

 

DR mode:

Nuc 90opulse

Pulse power
level (db)

Pulse
power (W)
Configuration
 
Sample Remarks
13C 1.2 3.3 136 λ/2 Adamantane line width 1.2Hz
1H .95 1.6 123 λ/2 Adamantane  
13C 1.6 5 96 λ/2 Glycine (CP) S/N 53 (16 scans)
1H 1.27 3.8 74 λ/2 Glycine  
19F 0.82 4.3 93 λ/4 pvdf  
13C 1.25 3.3 136 λ/4 pvdf  

 

Tuning ranges (tested on the bench; probe in double-resonance mode 1H-X)

λ /4 mode

61 →132 MHz

Includes: 14N(61.424), 33S(65.246), 189Os(66.006), 21Ne(67.102), 176Lu(69.114), 37Cl(69.324), 131Xe(70.073), 169Tm(70.465), 61Ni(75.956), 91Zr(79.019), 85Rb( 82.067), 35Cl (83.282), 135Ba( 84.443), 50V( 84.748), 15N( 86.163), 10B(91.321), 153Eu(93.330), 137Ba( 94.460), 175Lu( 96.934), 181Ta(101.912), 123Sb( 110.153), 133Cs(111.487), 138La(112.152), 17O(115.230), 9Be( 119.440), 139La(120.068), 6Li(125.087), 2H(130.480)

λ/2 mode

150 → 215 MHz

Includes: 77Se(162.108), 29Si(168.871), 127I(170.064), 207Pb( 177.825), 111Cd(180.332), 165Ho(181.390), 195Pt(182.723), 113In(185.859), 115In(186.257), 113Cd(188.642), 99Tc(191.321), 185Re(191.459), 187Re(193.389), 59Co(201.680), 121Sb(203.410), 69Ga(204.012), 159Tb(204.340), 45Sc(206.480), 93Nb(208.047), 55Mn(210.708), 151Eu(211.310), 79Br(212.959), 13C(213.733)

λ/2 mode + range coil

220 → 280 MHz

27Al (221.483), 123Te(222.443), 51V(223.575), 23Na(224.841), 63Cu(225.382), 81Br(229.555), 129Xe(236.387), 65Cu(241.431), 71Ga(259.222), 141Pr(260.270), 125Te(268.173), 11B(272.714), 115Sn(278.109), 87Rb(278.124), 117Sn(302.874), 119Sn(316.970), 7Li(330.342), 31P(344.086)