Until Anne's reign it is difficult, though possible, to identify 'Chief Ministers'. I have, therefore, begun listing the heads of administrations in 1702.

• 1689 William III
• 1702 Godolphin-Marlborough Anne
• 1710 Harley
• 1714 Stanhope George I
• 1717 Stanhope-Sutherland
• 1727 Stanhope-Sutherland George II
• 1721 Walpole
• 1742 Carteret
• 1744 Pelham
• 1746 Bath
• 1746 Pelham
• 1754 Newcastle
• 1756 Pitt-Devonshire
• 1757 Pitt-Newcastle
• 1760 George III
• 1761 Bute-Newcastle
• 1762 Bute
• 1763 Grenville
• 1765 Rockingham
• 1766 Chatham
• 1768 Grafton
• 1770 North
• Mar 1782 Rockingham
• July 1782 Shelburne
• Apr 1783 Fox-North
• Dec 1783 Pitt the Younger
• 1801 Addington
• 1804 Pitt
• 1806 Ministry of All the Talents
• 1807 Portland
• 1809 Perceval
• 1812 Liverpool
• 1820 George IV
• Apr 1827 Canning
• Aug 1827 Goderich
• 1828 Wellington
• 1830 Grey William IV